2,2′-(Hexane-1,6-diyl)diisoquinolinium tetrachloridozincate(II)

2,2′-(Hexane-1,6-diyl)diisoquinolinium tetrachloridozincate(II)

The asymmetric unit of the title compound, (C24H26N2)[ZnCl4], consists of two 2,2′-(hexane-1,6-diyl)diisoquinolinium cations and two [ZnCl4]2− complex anions. The [ZnCl4]2− anions have a distorted tetrahedral geometry. The dihedral angles between the isoquin...

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Main Authors: Pei-Hua Ma, Zhi-Fang Fan, Yun-Qian Zhang, Xin Xiao, Sai-Feng Xue
Format: Article
Language:English
Published: International Union of Crystallography 2009-06-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536809017693
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spelling doaj-3347dfd440184b43abe6f052b9c5cd692020-11-24T21:45:39ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682009-06-01656m655m65510.1107/S16005368090176932,2′-(Hexane-1,6-diyl)diisoquinolinium tetrachloridozincate(II)Pei-Hua MaZhi-Fang FanYun-Qian ZhangXin XiaoSai-Feng XueThe asymmetric unit of the title compound, (C24H26N2)[ZnCl4], consists of two 2,2′-(hexane-1,6-diyl)diisoquinolinium cations and two [ZnCl4]2− complex anions. The [ZnCl4]2− anions have a distorted tetrahedral geometry. The dihedral angles between the isoquinoline rings of the two cations are nearly equal [16.1 (2) and 16.3 (2)°]. In the crystal structure, the ordered linear formation is aggregated by weak intermolecular π–π stacking interactions between neighboring isoquinoline pyridine rings with a centroid–centroid distance of 3.779 (4) Å. http://scripts.iucr.org/cgi-bin/paper?S1600536809017693
collection DOAJ
language English
format Article
sources DOAJ
author Pei-Hua Ma
Zhi-Fang Fan
Yun-Qian Zhang
Xin Xiao
Sai-Feng Xue
spellingShingle Pei-Hua Ma
Zhi-Fang Fan
Yun-Qian Zhang
Xin Xiao
Sai-Feng Xue
2,2′-(Hexane-1,6-diyl)diisoquinolinium tetrachloridozincate(II)
Acta Crystallographica Section E
author_facet Pei-Hua Ma
Zhi-Fang Fan
Yun-Qian Zhang
Xin Xiao
Sai-Feng Xue
author_sort Pei-Hua Ma
title 2,2′-(Hexane-1,6-diyl)diisoquinolinium tetrachloridozincate(II)
title_short 2,2′-(Hexane-1,6-diyl)diisoquinolinium tetrachloridozincate(II)
title_full 2,2′-(Hexane-1,6-diyl)diisoquinolinium tetrachloridozincate(II)
title_fullStr 2,2′-(Hexane-1,6-diyl)diisoquinolinium tetrachloridozincate(II)
title_full_unstemmed 2,2′-(Hexane-1,6-diyl)diisoquinolinium tetrachloridozincate(II)
title_sort 2,2′-(hexane-1,6-diyl)diisoquinolinium tetrachloridozincate(ii)
publisher International Union of Crystallography
series Acta Crystallographica Section E
issn 1600-5368
publishDate 2009-06-01
description The asymmetric unit of the title compound, (C24H26N2)[ZnCl4], consists of two 2,2′-(hexane-1,6-diyl)diisoquinolinium cations and two [ZnCl4]2− complex anions. The [ZnCl4]2− anions have a distorted tetrahedral geometry. The dihedral angles between the isoquinoline rings of the two cations are nearly equal [16.1 (2) and 16.3 (2)°]. In the crystal structure, the ordered linear formation is aggregated by weak intermolecular π–π stacking interactions between neighboring isoquinoline pyridine rings with a centroid–centroid distance of 3.779 (4) Å.
url http://scripts.iucr.org/cgi-bin/paper?S1600536809017693
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AT yunqianzhang 22amp8242hexane16diyldiisoquinoliniumtetrachloridozincateii
AT xinxiao 22amp8242hexane16diyldiisoquinoliniumtetrachloridozincateii
AT saifengxue 22amp8242hexane16diyldiisoquinoliniumtetrachloridozincateii
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