Ion association with tetra-n-alkylammonium cations stabilizes higher-oxidation-state neptunium dioxocations
The electrochemical behaviour of redox-active metal cations foremost depends on the metal centre’s inner-sphere coordination environment. Here the authors show that electrolyte cations unexpectedly stabilize higher-oxidation-state neptunium dioxocations in water through extended-coordination sphere...
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Nature Publishing Group
2019-01-01
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Series: | Nature Communications |
Online Access: | https://doi.org/10.1038/s41467-018-07982-5 |
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doaj-3308ca4d4e8544f0907d71fa820c2c312021-05-11T12:30:04ZengNature Publishing GroupNature Communications2041-17232019-01-011011810.1038/s41467-018-07982-5Ion association with tetra-n-alkylammonium cations stabilizes higher-oxidation-state neptunium dioxocationsShanna L. Estes0Baofu Qiao1Geng Bang Jin2Chemical Sciences and Engineering Division, Argonne National LaboratoryChemical Sciences and Engineering Division, Argonne National LaboratoryChemical Sciences and Engineering Division, Argonne National LaboratoryThe electrochemical behaviour of redox-active metal cations foremost depends on the metal centre’s inner-sphere coordination environment. Here the authors show that electrolyte cations unexpectedly stabilize higher-oxidation-state neptunium dioxocations in water through extended-coordination sphere interactions.https://doi.org/10.1038/s41467-018-07982-5 |
collection |
DOAJ |
language |
English |
format |
Article |
sources |
DOAJ |
author |
Shanna L. Estes Baofu Qiao Geng Bang Jin |
spellingShingle |
Shanna L. Estes Baofu Qiao Geng Bang Jin Ion association with tetra-n-alkylammonium cations stabilizes higher-oxidation-state neptunium dioxocations Nature Communications |
author_facet |
Shanna L. Estes Baofu Qiao Geng Bang Jin |
author_sort |
Shanna L. Estes |
title |
Ion association with tetra-n-alkylammonium cations stabilizes higher-oxidation-state neptunium dioxocations |
title_short |
Ion association with tetra-n-alkylammonium cations stabilizes higher-oxidation-state neptunium dioxocations |
title_full |
Ion association with tetra-n-alkylammonium cations stabilizes higher-oxidation-state neptunium dioxocations |
title_fullStr |
Ion association with tetra-n-alkylammonium cations stabilizes higher-oxidation-state neptunium dioxocations |
title_full_unstemmed |
Ion association with tetra-n-alkylammonium cations stabilizes higher-oxidation-state neptunium dioxocations |
title_sort |
ion association with tetra-n-alkylammonium cations stabilizes higher-oxidation-state neptunium dioxocations |
publisher |
Nature Publishing Group |
series |
Nature Communications |
issn |
2041-1723 |
publishDate |
2019-01-01 |
description |
The electrochemical behaviour of redox-active metal cations foremost depends on the metal centre’s inner-sphere coordination environment. Here the authors show that electrolyte cations unexpectedly stabilize higher-oxidation-state neptunium dioxocations in water through extended-coordination sphere interactions. |
url |
https://doi.org/10.1038/s41467-018-07982-5 |
work_keys_str_mv |
AT shannalestes ionassociationwithtetranalkylammoniumcationsstabilizeshigheroxidationstateneptuniumdioxocations AT baofuqiao ionassociationwithtetranalkylammoniumcationsstabilizeshigheroxidationstateneptuniumdioxocations AT gengbangjin ionassociationwithtetranalkylammoniumcationsstabilizeshigheroxidationstateneptuniumdioxocations |
_version_ |
1721444682519543808 |