Novel Cerium Bisphosphinate Coordination Polymer and Unconventional Metal–Organic Framework

The first Ce(III)-based coordination polymer ICR-9 (ICR stands for Inorganic Chemistry Řež), with the formula Ce2(C8H10P2O4)3, containing ditopic phenylene-1,4-bi...

Full description

Bibliographic Details
Main Authors:	Jan Rohlíček, Daniel Bůžek, Petr Brázda, Libor Kobera, Jan Hynek, Jiří Brus, Kamil Lang, Jan Demel
Format:	Article
Language:	English
Published:	MDPI AG 2019-06-01
Series:	Crystals
Subjects:	coordination polymer Cerium defects amorphous porosity electron diffraction tomography solid state NMR
Online Access:	https://www.mdpi.com/2073-4352/9/6/303

id	doaj-32fe25e9980d4f7fa76c517d90848009
record_format	Article
spelling	doaj-32fe25e9980d4f7fa76c517d908480092020-11-24T21:27:54ZengMDPI AGCrystals2073-43522019-06-019630310.3390/cryst9060303cryst9060303Novel Cerium Bisphosphinate Coordination Polymer and Unconventional Metal–Organic FrameworkJan Rohlíček0Daniel Bůžek1Petr Brázda2Libor Kobera3Jan Hynek4Jiří Brus5Kamil Lang6Jan Demel7Institute of Physics of the Czech Academy of Sciences, 18221 Prague, Czech RepublicInstitute of Inorganic Chemistry of the Czech Academy of Sciences, Husinec-Řež 1001, 250 68 Řež, Czech RepublicInstitute of Physics of the Czech Academy of Sciences, 18221 Prague, Czech RepublicInstitute of Macromolecular Chemistry of the Czech Academy of Sciences, Heyrovského nám. 2, 162 06 Prague 6, Czech RepublicInstitute of Inorganic Chemistry of the Czech Academy of Sciences, Husinec-Řež 1001, 250 68 Řež, Czech RepublicInstitute of Macromolecular Chemistry of the Czech Academy of Sciences, Heyrovského nám. 2, 162 06 Prague 6, Czech RepublicInstitute of Inorganic Chemistry of the Czech Academy of Sciences, Husinec-Řež 1001, 250 68 Řež, Czech RepublicInstitute of Inorganic Chemistry of the Czech Academy of Sciences, Husinec-Řež 1001, 250 68 Řež, Czech RepublicThe first Ce(III)-based coordination polymer ICR-9 (ICR stands for Inorganic Chemistry Řež), with the formula Ce<sub>2</sub>(C<sub>8</sub>H<sub>10</sub>P<sub>2</sub>O<sub>4</sub>)<sub>3</sub>, containing ditopic phenylene-1,4-bis(methylphosphinic acid) linker, was synthetized under solvothermal conditions. The crystal structure, solved using electron diffraction tomography (EDT), revealed 2D layers of octahedrally coordinated cerium atoms attached together through O-P-O bridges. The structure is nonporous, however, the modification of synthetic conditions led to unconventional metal−organic framework (or defective amorphous phase) with a specific surface area up to approximately 400 m<sup>2</sup> g<sup>-1</sup>.https://www.mdpi.com/2073-4352/9/6/303coordination polymerCeriumdefectsamorphousporosityelectron diffraction tomographysolid state NMR
collection	DOAJ
language	English
format	Article
sources	DOAJ
author	Jan Rohlíček Daniel Bůžek Petr Brázda Libor Kobera Jan Hynek Jiří Brus Kamil Lang Jan Demel
spellingShingle	Jan Rohlíček Daniel Bůžek Petr Brázda Libor Kobera Jan Hynek Jiří Brus Kamil Lang Jan Demel Novel Cerium Bisphosphinate Coordination Polymer and Unconventional Metal–Organic Framework Crystals coordination polymer Cerium defects amorphous porosity electron diffraction tomography solid state NMR
author_facet	Jan Rohlíček Daniel Bůžek Petr Brázda Libor Kobera Jan Hynek Jiří Brus Kamil Lang Jan Demel
author_sort	Jan Rohlíček
title	Novel Cerium Bisphosphinate Coordination Polymer and Unconventional Metal–Organic Framework
title_short	Novel Cerium Bisphosphinate Coordination Polymer and Unconventional Metal–Organic Framework
title_full	Novel Cerium Bisphosphinate Coordination Polymer and Unconventional Metal–Organic Framework
title_fullStr	Novel Cerium Bisphosphinate Coordination Polymer and Unconventional Metal–Organic Framework
title_full_unstemmed	Novel Cerium Bisphosphinate Coordination Polymer and Unconventional Metal–Organic Framework
title_sort	novel cerium bisphosphinate coordination polymer and unconventional metal–organic framework
publisher	MDPI AG
series	Crystals
issn	2073-4352
publishDate	2019-06-01
description	The first Ce(III)-based coordination polymer ICR-9 (ICR stands for Inorganic Chemistry Řež), with the formula Ce<sub>2</sub>(C<sub>8</sub>H<sub>10</sub>P<sub>2</sub>O<sub>4</sub>)<sub>3</sub>, containing ditopic phenylene-1,4-bis(methylphosphinic acid) linker, was synthetized under solvothermal conditions. The crystal structure, solved using electron diffraction tomography (EDT), revealed 2D layers of octahedrally coordinated cerium atoms attached together through O-P-O bridges. The structure is nonporous, however, the modification of synthetic conditions led to unconventional metal−organic framework (or defective amorphous phase) with a specific surface area up to approximately 400 m<sup>2</sup> g<sup>-1</sup>.
topic	coordination polymer Cerium defects amorphous porosity electron diffraction tomography solid state NMR
url	https://www.mdpi.com/2073-4352/9/6/303
work_keys_str_mv	AT janrohlicek novelceriumbisphosphinatecoordinationpolymerandunconventionalmetalorganicframework AT danielbuzek novelceriumbisphosphinatecoordinationpolymerandunconventionalmetalorganicframework AT petrbrazda novelceriumbisphosphinatecoordinationpolymerandunconventionalmetalorganicframework AT liborkobera novelceriumbisphosphinatecoordinationpolymerandunconventionalmetalorganicframework AT janhynek novelceriumbisphosphinatecoordinationpolymerandunconventionalmetalorganicframework AT jiribrus novelceriumbisphosphinatecoordinationpolymerandunconventionalmetalorganicframework AT kamillang novelceriumbisphosphinatecoordinationpolymerandunconventionalmetalorganicframework AT jandemel novelceriumbisphosphinatecoordinationpolymerandunconventionalmetalorganicframework
_version_	1725972567583358976

Novel Cerium Bisphosphinate Coordination Polymer and Unconventional Metal–Organic Framework

Similar Items