Crystal structures of three copper(II)–2,2′-bipyridine (bpy) compounds, [Cu(bpy)2(H2O)][SiF6]·4H2O, [Cu(bpy)2(TaF6)2] and [Cu(bpy)3][TaF6]2 and a related coordination polymer, [Cu(bpy)(H2O)2SnF6]n

Crystal structures of three copper(II)–2,2′-bipyridine (bpy) compounds, [Cu(bpy)2(H2O)][SiF6]·4H2O, [Cu(bpy)2(TaF6)2] and [Cu(bpy)3][TaF6]2 and a related coordination polymer, [Cu(bpy)(H2O)2SnF6]n

We report the hydrothermal syntheses and crystal structures of aquabis(2,2′-bipyridine-κ2N,N′)copper(II) hexafluoridosilicate tetrahydrate, [Cu(bpy)2(H2O)][SiF6]·4H2O (bpy is 2,2′-bipyridine, C10H8N2), (I), bis(2,2′-bipyridine-3κ2N,N′)-di-μ-fluorido-1:3κ2F:F;2:3κ2F:F-decafluorido-1κ5F,2κ5F-ditantalu...

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Bibliographic Details
Main Authors: Matthew L. Nisbet, Emily Hiralal, Kenneth R. Poeppelmeier
Format: Article
Language:English
Published: International Union of Crystallography 2021-02-01
Series:Acta Crystallographica Section E: Crystallographic Communications
Subjects:
crystal structure
hydrothermal synthesis
racemic compounds
copper
main group
d0 early transition metal
Online Access:http://scripts.iucr.org/cgi-bin/paper?S2056989021000633

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