Tetrakis(μ-benzoato-κ2O:O′)bis[(piperidine-κN)rhodium]

Tetrakis(μ-benzoato-κ2O:O′)bis[(piperidine-κN)rhodium]

The title compound, [Rh2(C7H5O2)4(C5H11N)2], an adduct of dimeric rhodium(II) benzoate with piperidine, was prepared. The complex lies across an inversion centre with the unique RhII ion in a slightly distorted octahedral coordination environment.

Bibliographic Details
Main Authors:	Detlef Selent, Hans-Joachim Drexler
Format:	Article
Language:	English
Published:	International Union of Crystallography 2017-02-01
Series:	IUCrData
Subjects:	crystal structure rhodium complex benzoate piperidine
Online Access:	http://scripts.iucr.org/cgi-bin/paper?S241431461700205X

Similar Items

Crystal structure of catena-poly[calcium-di-μ3-benzoato-κ6O,O′:O-μ2-(dimethyl sulfoxide)-κ2O:O]
by: Anna S. Voronova, et al.
Published: (2015-08-01)

Bis(μ-benzoato-κ2O:O′)bis(benzoato-κO)octabutyldi-μ3-oxido-tetratin(IV)
by: Hans Reuter, et al.
Published: (2017-03-01)

Crystal structure of tetrakis[μ-2-(methoxycarbonyl)benzoato-κ2O1:O1′]bis[(N,N-dimethylformamide-κO)copper(II)](Cu—Cu) dimethylformamide disolvate
by: Jinglin Wang, et al.
Published: (2018-05-01)

Tetrakis[μ2-5-nitro-2-(phenylsulfanyl)benzoato-κ2O:O′]bis[(acetonitrile-κN)copper(II)]
by: Danrui Xu, et al.
Published: (2020-06-01)

{2-[Bis(2,4-di-tert-butylphenoxy)phosphanyloxy-κP]-3,5-di-tert-butylphenyl-κC1}{3,3′-di-tert-butyl-5,5′-dimethoxy-2,2′-bis[(1,1,2,2-tetraphenylethane-1,2-dioxy)phosphanyloxy-κP]biphenyl}rhodium(I) toluene-d8 2.7-solvate
by: Detlef Selent, et al.
Published: (2016-12-01)

Crystal structure and Hirshfeld surface analysis of bis(benzoato-κ2O,O′)[bis(pyridin-2-yl-κN)amine]nickel(II)
by: Phichitra Phiokliang, et al.
Published: (2019-09-01)

Bis(μ2-benzoato-κ2O:O′)bis[(benzoato-κ2O,O′)bis(4,4′-bipyridine-κN)cobalt(II)]–benzoic acid (1/6)
by: Rodolfo Peña-Rodríguez, et al.
Published: (2014-01-01)

(η2,η2-Cycloocta-1,5-diene)[2-(diphenylphosphanylmethyl)pyridine-κ2N,P]rhodium(I) tetrafluoridoborate 1,2-dichloroethane monosolvate
by: Siping Wei, et al.
Published: (2016-08-01)

The crystal structures of tetrakis(μ-n-butyrato-κ2O:O′)bis[bromidorhenium(III)] and tetrakis(μ-n-butyrato-κ2O:O′)bis[chloridorhenium(III)] acetonitrile disolvate
by: Carly R. Reed, et al.
Published: (2015-12-01)

Crystal structure of di-μ-benzato-κ4O:O′-bis[aqua(benzato-κO)(benzato-κ2O,O′)(2,2′:6′,2′′-terpyridine-κ3N,N′,N′′)europium(III)]–benzoic acid (1/2)
by: Frankie White, et al.
Published: (2014-09-01)

Piperidine nucleus in the field of drug discovery
by: Mennatallah Mahmoud Abdelshaheed, et al.
Published: (2021-09-01)

(η4-1,5-Cyclooctadiene)[(R)-(+)-5,5′,6,6′,7,7′,8,8′-octahydro-2,2′-bis(diphenylphosphanyl)-1,1′-binaphthyl-κ2P,P′]rhodium(I) tetrafluoroborate 0.72-pentane 0.56-methanol solvate
by: Cornelia Pribbenow, et al.
Published: (2017-09-01)

Crystal structure of aquabis[4-(methylsulfanyl)benzoato-κO](1,10-phenanthroline-κ2N,N′)copper(II) monohydrate
by: Jin-Li Zhu, et al.
Published: (2015-08-01)

Oxyamination d'alcoxyamines catalysée par le rhodium(iii) - Agrandissement de pyrrolidines en présence de sels d'argent
by: Escudero, Julien
Published: (2016)

Bis(μ2-benzoato-κ2O,O′)bis(benzoato-κO)bis(ethanol-κO)bis(μ3-hydroxido)hexakis(μ-pyrazolato-κ2N,N′)hexacopper(II) ethanol disolvate
by: Marisol Ledezma-Gairaud, et al.
Published: (2019-09-01)

Crystal structure of dichlorido[2-(1H-imidazol-2-yl-κN3)imidazolato-κN]bis(tri-n-butylphosphane-κP)rhodium(III)
by: Jin-Long, et al.
Published: (2014-11-01)

Crystal structures of fac-trichloridotris(trimethylphosphane-κP)rhodium(III) monohydrate and fac-trichloridotris(trimethylphosphane-κP)rhodium(III) methanol hemisolvate: rhodium structures that are isotypic with their iridium analogs
by: Joseph S. Merola, et al.
Published: (2015-02-01)

Crystal structure of tetrakis(μ-caproato-κ2O:O′)bis[(4-cyanopyridine-κN1)copper(II)]
by: Sukanya Baruah, et al.
Published: (2015-11-01)

Crystal structure of trans-diaquabis(4-cyanobenzoato-κO)bis(N,N-diethylnicotinamide-κN)zinc(II)
by: Nurcan Akduran, et al.
Published: (2016-10-01)

Crystal structure of catena-poly[[aquabis(4-cyanobenzoato-κO)copper(II)]-μ-N,N-diethylnicotinamide-κ2N1:O]
by: Nurcan Akduran, et al.
Published: (2016-08-01)

Crystal structure of tetrakis(μ-n-butyrato-κ2O:O′)bis[chloridorhenium(III)](Re—Re)
by: Michael P. Thomson, et al.
Published: (2014-10-01)

Crystal structure of tetrakis(μ-2,4,6-trimethylbenzoato-κ2O:O′)bis[(nicotinamide-κN1)copper(II)]
by: Gülçin Şefiye Aşkın, et al.
Published: (2015-08-01)

Poly[diaqua[μ4-2-(carboxylatomethoxy)benzoato][μ2-2-(carboxylatomethoxy)benzoato]dicadmium(II)]
by: Gabrielle J. Gaskin, et al.
Published: (2019-07-01)

Crystal structure and Hirshfeld surface analysis of hexakis(μ-benzoato-κ2O:O′)bis(pyridine-3-carbonitrile-κN1)trizinc(II)
by: Tuncer Hökelek, et al.
Published: (2017-12-01)

(μ-Acetato-κ2O:O′)[μ-2,6-bis({bis[(pyridin-2-yl-κN)methyl]amino-κN}methyl)-4-methylphenolato-κ2O:O](methanol-κO)dizinc bis(perchlorate)
by: Biswanath Das, et al.
Published: (2014-04-01)

Bis (ditertiaryphosphine) complexes of rhodium, and catalytic asymmetric hydrogenation
by: Mahajan, Devinder
Published: (2010)

Structure of tetrakis(μ-decanoato-κ2O:O′)bis[(4-methylpyridine-κN)copper(II)], a dimeric copper(II) complex
by: Monsumi Gogoi, et al.
Published: (2020-11-01)

Studies in the synthesis of piperidine alkaloids
by: Mosts, R. C.
Published: (1987)

Thermal stability and electrochemical behaviour of Tetrakis-μ-benzoatodicopper(II)
by: Mohamadin Mohammad, et al.
Published: (2010-10-01)

Crystal structure of tetrakis(μ-N-phenylacetamidato)-κ4N:O;κ4O:N-bis[(2-methylbenzonitrile-κN)rhodium(II)](Rh—Rh)
by: Cassandra T. Eagle, et al.
Published: (2014-09-01)

trans-Dichloridotetrakis(pyridine-κN)rhodium(III) chloride methanol tetrasolvate
by: Takayoshi Suzuki, et al.
Published: (2018-10-01)

Bis(μ2-diphenylphosphinamide-κ2O:O)bis[bis(diphenylphosphinamide-κO)lithium] dichloride acetonitrile disolvate
by: Ai-Hong Li, et al.
Published: (2014-06-01)

Di-μ-dimethylformamide-κ4O:O-μ-tetrahydrofuran-κ2O:O-bis[(tetrahydrofuran-κO)sodium(I)] bis(μ-3,6-dichlorobenzene-1,2-dithiolato-κ3S,S′:S)bis[(3,6-dichlorobenzene-1,2-dithiolato-κ2S,S′)iron(III)]
by: Jesús Barrio, et al.
Published: (2016-04-01)

Synthetic approaches to functionalised piperidines
by: Woods, Gordon Alexander
Published: (1999)

Acetophenone Derivatives; N-Diphenylmethyl and N-Fluorenyl Piperidines
by: Middleton, William J.
Published: (1949)

μ-Carbonyl-bis(carbonyl{η5-[tricarbonyl(η6-2-methylindenyl)chromium(0)]rhodium(III)})(Rh—Rh)
by: Christophe Werlé, et al.
Published: (2019-05-01)

An Efficient Synthesis of Aldohexose-Derived Piperidine Nitrones: Precursors of Piperidine Iminosugars
by: Chu-Yi Yu, et al.
Published: (2013-05-01)

The preparative synthetic approach to 4-(triﬂuoromethoxy)piperidine and 4-(triﬂuoromethoxymethyl)piperidine
by: Ivan G. Logvinenko, et al.
Published: (2021-03-01)

Crystal structure of di-μ-hydroxido-κ4O:O-bis[bis(acetylacetonato-κ2O,O′)cobalt(III)]
by: Casseday P. Richers, et al.
Published: (2015-08-01)

Pharmacological screening of synthetic piperidine derivatives
by: Naicker, Leeantha
Published: (2016)