2-(2-Amino-4-nitrophenyl)-7-nitro-4H-3,1-benzoxazin-4-one

2-(2-Amino-4-nitrophenyl)-7-nitro-4H-3,1-benzoxazin-4-one

In the title compound, C14H8N4O6, the benzoxazin-4-one fused-ring system (r.m.s. deviation = 0.018 Å) is coplanar with the attached benzene ring [dihedral angle = 0.81 (4)°], there being an intramolecular N—H...N hydrogen bond between them. Each nitro group is twisted out of the plane of the attache...

Full description

Bibliographic Details
Main Authors:	Edward R. T. Tiekink, James L. Wardell
Format:	Article
Language:	English
Published:	International Union of Crystallography 2014-02-01
Series:	Acta Crystallographica Section E
Online Access:	http://scripts.iucr.org/cgi-bin/paper?S1600536814000609

Similar Items

(S)-6-Chloro-4-cyclopropylethynyl-4-trifluoromethyl-1H-3,1-benzoxazin-2(4H)-one
by: James L. Wardell, et al.
Published: (2009-12-01)

2-Phenyl-4H-3,1-benzoxazin-4-one
by: Helen P. Kavitha, et al.
Published: (2009-01-01)

5′-Nitro-1,4-dihydrospiro[3,1-benzoxazine-2,3′-indolin]-2′-one
by: Y. AaminaNaaz, et al.
Published: (2018-05-01)

(E)-1-(4-Nitrophenyl)-2-(4-{[(E)-2-(4-nitrophenyl)hydrazinylidene]methyl}benzylidene)hydrazine dihydrate
by: Edward R. T. Tiekink, et al.
Published: (2010-01-01)

4-[(Dimethylamino)methylidene]-2-(4-nitrophenyl)-1,3-oxazol-5(4H)-one
by: Gilberto A. Romeiro, et al.
Published: (2010-06-01)

2-(4H-1,3-Benzoxazin-2-yl)phenol
by: James L. Wardell, et al.
Published: (2009-12-01)

(4S*)-2-Methylamino-3-nitro-4-(4-nitrophenyl)-5,6,7,8-tetrahydro-4H-chromen-5-one
by: P. Narayanan, et al.
Published: (2013-09-01)

4-Benzyl-7-chloro-2H-1,4-benzoxazin-3(4H)-one
by: Chen-Guang Zhao, et al.
Published: (2009-05-01)

7-Chloro-4-phenethyl-2H-1,4-benzoxazin-3(4H)-one
by: Ming-Jun Chen, et al.
Published: (2009-04-01)

1-Methyl-4H-3,1-benzoxazine-2,4(1H)dione
by: Benny C. Chan, et al.
Published: (2010-03-01)

Facile Synthesis and Herbicidal Evaluation of 4H-3,1-Benzoxazin-4-ones and 3H-Quinazolin-4-ones with 2-Phenoxymethyl Substituents
by: Aidong Zhang, et al.
Published: (2012-03-01)

3,5-Dimethyl-1-(4-nitrophenyl)-1H-pyrazole
by: Edward R. T. Tiekink, et al.
Published: (2012-04-01)

4-Formyl-2-nitrophenyl 3-nitro-2-methylbenzoate
by: Rodolfo Moreno-Fuquen, et al.
Published: (2014-01-01)

2-[N-(3-Amino-4-nitrophenyl)carboximidoyl]phenol
by: Gholam Hossein Shahverdizadeh, et al.
Published: (2011-11-01)

6-Chloro-2H-1,4-benzoxazin-3(4H)-one
by: Yong-Sheng Xie, et al.
Published: (2008-12-01)

The Uses of 2-Ethoxy-(4H)-3,1-benzoxazin-4-one in the Synthesis of Some Quinazolinone Derivatives of Antimicrobial Activity
by: Fakhry A. El-Bassiouny, et al.
Published: (2011-07-01)

Synthesis of Benzoxazinone Derivatives: A New Route to 2 (N Phthaloylmethyl)-4H-3,1-benzoxazin-4-one
by: Sohrab Abdollahi, et al.
Published: (2004-07-01)

7-Hydroxy-3-(4-nitrophenyl)-2H-chromen-2-one
by: Shashikanth Walki, et al.
Published: (2016-03-01)

6-Chloro-8-methyl-4H-3,1-benzoxazine-2,4(1H)-dione
by: Yan-Ling Zhou, et al.
Published: (2010-05-01)

(1R*,2S*)-2-Nitro-1-(4-nitrophenyl)propanol
by: Jun-na Zhang, et al.
Published: (2012-03-01)

8-Chloro-4-cyclohexyl-2H-1,4-benzoxazin-3(4H)-one
by: Zhu-Bo Li, et al.
Published: (2009-04-01)

2-Amino-4-methylpyridinium 2-(4-nitrophenyl)acetate
by: P. Sivakumar, et al.
Published: (2016-08-01)

4-Nitro-N-(3-nitrophenyl)benzamide
by: Colin R. Taylor, et al.
Published: (2011-10-01)

tert-Butyl 6-amino-3,4-dihydro-2H-1,4-benzoxazine-4-carboxylate
by: Yao-Yuan Zhou, et al.
Published: (2010-12-01)

Silica-bound benzoyl chloride mediated the solid-phase synthesis of 4H-3,1-benzoxazin-4-ones
by: Kurosh Rad-Moghadam, et al.
Published: (2009-04-01)

2,3-Dibromo-3-(5-nitro-2-furyl)-1-(4-nitrophenyl)propan-1-one
by: Balakrishna Kalluraya, et al.
Published: (2010-12-01)

2-{(E)-1-[2-(4-Nitrophenyl)hydrazin-1-ylidene]ethyl}benzene-1,3-diol
by: Edward R. T. Tiekink, et al.
Published: (2012-03-01)

3-(4-Bromophenyl)-4-[2-(4-nitrophenyl)hydrazinyl]furan-2(5H)-one
by: Zhu-Ping Xiao, et al.
Published: (2011-11-01)

An efficient synthesis of 2H-1,4-benzoxazin-3(4H)-ones via Smiles rearrangement
by: Jongphil Kang, et al.
Published: (2008-08-01)

6-Methoxy-2-phenyl-4,4a,6,7,8,8a-hexahydro-2H-pyrano[3,2-d][1,3]dioxine-7,8-diyl bis(4-methylbenzene-1-sulfonate)
by: James L. Wardell, et al.
Published: (2012-03-01)

2-Amino-4-methylpyridin-1-ium 2-(4-nitrophenyl)acetate
by: P. Sivakumar, et al.
Published: (2016-09-01)

Synthesis and biological evaluation of novel cytotoxic heterocylic compounds : furo[2,3-b]naphthoquinones and 2-aryl-4H-3,1-benzoxazin-4-ones
by: Perry, Philip J.
Published: (1996)

(4-Chlorobenzoyl)(4-chlorophenyl)amino 3-(2-nitrophenyl)propanoate
by: Yi-lan Ding, et al.
Published: (2013-04-01)

7,7-Dimethyl-2-methylamino-4-(4-methylphenyl)-3-nitro-7,8-dihydro-4H-chromen-5(6H)-one
by: S. Antony Inglebert, et al.
Published: (2014-06-01)

Reactivity of 4H-3,1-benzoxazin-4-ones towards nitrogen and carbon nucleophilic reagents: applications to the synthesis of new Heterocycles
by: H.M.F. Madkour
Published: (2004-03-01)

(2E)-N&#8242;-Benzoyl-3-(4-nitrophenyl)prop-2-enohydrazide
by: Samir A. Carvalho, et al.
Published: (2010-01-01)

Crystal structures of 2-(4-nitrophenyl)-3-phenyl-2,3-dihydro-4H-1,3-benzothiazin-4-one and 2-(2-nitrophenyl)-3-phenyl-2,3-dihydro-4H-1,3-benzothiazin-4-one
by: Hemant Yennawar, et al.
Published: (2015-04-01)

Ethyl 5-amino-1-(4-chloro-2-nitrophenyl)-1H-pyrazole-4-carboxylate
by: Hamid Latif Siddiqui, et al.
Published: (2009-02-01)

(S)-2-(3-Nitrophenyl)-1,2-dihydroquinazolin-4(3H)-one
by: Yanqiu Fan, et al.
Published: (2008-02-01)

Highly efficient synthesis of 4H-3,1-benzoxazines by the electrophilic cyclization reaction
by: Ho-Chuan Shen, et al.
Published: (2010)