Effect of Film-Forming Amines on the Acidic Stress-Corrosion Cracking Resistance of Steam Turbine Steel

This work evaluates the effect of film-forming amines (FFA) on the acidic stress-corrosion cracking (SCC) resistance of NiCrMoV turbine steel. Contact angle measurements show an increased hydrophobicity of the surface when coating the steel with oleyl propylene diamine (OLDA). According to potentiod...

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Main Authors: Tim De Seranno, Ellen Lambrechts, Evelyn De Meyer, Wolfgang Hater, Nathalie De Geyter, Arne R. D. Verliefde, Tom Depover, Kim Verbeken
Format: Article
Language:English
Published: MDPI AG 2020-12-01
Series:Metals
Subjects:
XPS
SEM
Online Access:https://www.mdpi.com/2075-4701/10/12/1628
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spelling doaj-3195960ab8dd4b2f83df0105987262572020-12-05T00:03:22ZengMDPI AGMetals2075-47012020-12-01101628162810.3390/met10121628Effect of Film-Forming Amines on the Acidic Stress-Corrosion Cracking Resistance of Steam Turbine SteelTim De Seranno0Ellen Lambrechts1Evelyn De Meyer2Wolfgang Hater3Nathalie De Geyter4Arne R. D. Verliefde5Tom Depover6Kim Verbeken7Department of Materials, Textiles and Chemical Engineering, Research Unit Sustainable Materials Science, Ghent University, Technologiepark 46, 9052 Zwijnaarde, BelgiumDepartment of Materials, Textiles and Chemical Engineering, Research Unit Sustainable Materials Science, Ghent University, Technologiepark 46, 9052 Zwijnaarde, BelgiumDepartment of Green Chemistry and Technology, Ghent University, Coupure Links 653, 9000 Ghent, BelgiumKurita Europe GmbH, Niederheider Straße 22, D-40589 Düsseldorf, GermanyDepartment of Applied Physics, Research Unit Plasma Technology, Ghent University, Sint-Pietersnieuwstraat 41, 9000 Ghent, BelgiumDepartment of Green Chemistry and Technology, Ghent University, Coupure Links 653, 9000 Ghent, BelgiumDepartment of Materials, Textiles and Chemical Engineering, Research Unit Sustainable Materials Science, Ghent University, Technologiepark 46, 9052 Zwijnaarde, BelgiumDepartment of Materials, Textiles and Chemical Engineering, Research Unit Sustainable Materials Science, Ghent University, Technologiepark 46, 9052 Zwijnaarde, BelgiumThis work evaluates the effect of film-forming amines (FFA) on the acidic stress-corrosion cracking (SCC) resistance of NiCrMoV turbine steel. Contact angle measurements show an increased hydrophobicity of the surface when coating the steel with oleyl propylene diamine (OLDA). According to potentiodynamic measurements and post-mortem scanning electron microscopy (SEM) analysis, anodic dissolution and hydrogen embrittlement still occur when the steel is FFA coated. In situ constant extension rate testing (CERT) in acidic aqueous environment at elevated temperature of FFA-coated steel shows a ductility gain compared to non-coated steel, explained by a decrease in both corrosion rate and hydrogen uptake.https://www.mdpi.com/2075-4701/10/12/1628film-forming aminesstress-corrosion crackinglow alloy steelacid solutionsXPSSEM
collection DOAJ
language English
format Article
sources DOAJ
author Tim De Seranno
Ellen Lambrechts
Evelyn De Meyer
Wolfgang Hater
Nathalie De Geyter
Arne R. D. Verliefde
Tom Depover
Kim Verbeken
spellingShingle Tim De Seranno
Ellen Lambrechts
Evelyn De Meyer
Wolfgang Hater
Nathalie De Geyter
Arne R. D. Verliefde
Tom Depover
Kim Verbeken
Effect of Film-Forming Amines on the Acidic Stress-Corrosion Cracking Resistance of Steam Turbine Steel
Metals
film-forming amines
stress-corrosion cracking
low alloy steel
acid solutions
XPS
SEM
author_facet Tim De Seranno
Ellen Lambrechts
Evelyn De Meyer
Wolfgang Hater
Nathalie De Geyter
Arne R. D. Verliefde
Tom Depover
Kim Verbeken
author_sort Tim De Seranno
title Effect of Film-Forming Amines on the Acidic Stress-Corrosion Cracking Resistance of Steam Turbine Steel
title_short Effect of Film-Forming Amines on the Acidic Stress-Corrosion Cracking Resistance of Steam Turbine Steel
title_full Effect of Film-Forming Amines on the Acidic Stress-Corrosion Cracking Resistance of Steam Turbine Steel
title_fullStr Effect of Film-Forming Amines on the Acidic Stress-Corrosion Cracking Resistance of Steam Turbine Steel
title_full_unstemmed Effect of Film-Forming Amines on the Acidic Stress-Corrosion Cracking Resistance of Steam Turbine Steel
title_sort effect of film-forming amines on the acidic stress-corrosion cracking resistance of steam turbine steel
publisher MDPI AG
series Metals
issn 2075-4701
publishDate 2020-12-01
description This work evaluates the effect of film-forming amines (FFA) on the acidic stress-corrosion cracking (SCC) resistance of NiCrMoV turbine steel. Contact angle measurements show an increased hydrophobicity of the surface when coating the steel with oleyl propylene diamine (OLDA). According to potentiodynamic measurements and post-mortem scanning electron microscopy (SEM) analysis, anodic dissolution and hydrogen embrittlement still occur when the steel is FFA coated. In situ constant extension rate testing (CERT) in acidic aqueous environment at elevated temperature of FFA-coated steel shows a ductility gain compared to non-coated steel, explained by a decrease in both corrosion rate and hydrogen uptake.
topic film-forming amines
stress-corrosion cracking
low alloy steel
acid solutions
XPS
SEM
url https://www.mdpi.com/2075-4701/10/12/1628
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