OXIDATION OF 2-PICOLINE OF OZONE IN THE LIQUID PHASE

• Main Authors: P. Yu. Andreev, I. P. Pogorelova, M. V. Shipidchenko
• Format: Article
• Language: English
• Published: Odessa I. I. Mechnikov National University 2015-02-01
• Series: Vìsnik Odesʹkogo Nacìonalʹnogo Unìversitetu: Hìmìâ
• Subjects: окиснення, озон, 2-піколін, оцтова кислота, 2-піколінова кислота, пероксидні сполуки
• Online Access: http://heraldchem.onu.edu.ua/article/view/38106

Study of the reactions of 2-picoline with ozone in acetic acid solution. It is established that ozone reacts with 2-picoline in three ways: by heteroaromatic ring, a free pair of electrons on the nitrogen atom and the methyl group. The main products of destructive oxidation of heteroaromatic rings are peroxide compounds. Among the products of aromatic character identified 2-picoline-N-oxide and 2-picolinic acid. Reaction of 2-picoline with ozone in acetic acid solution is first order in each of the initial reagents.