High efficient oxygen reduction performance of Fe/Fe3C nanoparticles in situ encapsulated in nitrogen-doped carbon via a novel microwave-assisted carbon bath method

• Main Authors: Mincong Liu, Xue Yin, Xuhong Guo, Libing Hu, Huifang Yuan, Gang Wang, Fu Wang, Long Chen, Lili Zhang, Feng Yu
• Format: Article
• Language: English
• Published: KeAi Communications Co., Ltd. 2019-06-01
• Series: Nano Materials Science
• Online Access: http://www.sciencedirect.com/science/article/pii/S2589965119300285
• ISSN: 2589-9651

Fe-based carbon materials are widely considered promising to replace Pt/C as next-generation electrocatalysts towards oxygen reduction reaction (ORR). However, the preparation of Fe-based carbon materials is still carried out by conventional heating method (CHM). Herein, a novel microwave-assisted carbon bath method (MW-CBM) was proposed, which only took 35 min to synthesize Fe/Fe3C nanoparticles encapsulated in N-doped carbon layers derived from Prussian blue (PB). The catalyst contained large specific surface area and mesoporous structure, abundant Fe-Nx and CN active sites, unique core-shell structure. Due to the synergistic effects of these features, the as-prepared Fe/Fe3C@NC-2 displayed outstanding ORR activity with onset potential of 0.98 VRHE and half-wave potential of 0.87 VRHE, which were more positive than 20 wt.% Pt/C (0.93 VRHE and 0.82 VRHE). Besides, Fe/Fe3C@NC-2 gave a better stability and methanol tolerance than Pt/C towards ORR in alkaline media, too. Keywords: Fe/Fe3C nanoparticles, Prussian blue, Microwave, Carbon bath method, Oxygen reduction reaction