Synthesis of Ash Derived Co/Zeolite Catalyst for Hydrogen Rich Syngas Production via Partial Oxidation of Methane

• Main Authors: Amer Zaffar, Bilal Alam Khan, Asif Hussain Khoja, Uneeb Masood Khan, Qassam Sarmad, Muhammad Taqi Mehran, Salman Raza Naqvi, Majid Ali
• Format: Article
• Language: English
• Published: Diponegoro University 2021-09-01
• Series: Bulletin of Chemical Reaction Engineering & Catalysis
• Subjects: partial oxidation of methane (pom); zeolite-4a; hydrogen production; syngas
• Online Access: https://ejournal2.undip.ac.id/index.php/bcrec/article/view/10614

The objective of this study was to analyze the catalytic performance of series of cobalt-modified Zeolite-4A supported catalysts for the syngas (CO and H2) production at 800 °C via the partial oxidation of methane (POM). The Co/Zeolite-4A catalyst was synthesized using a two-step hydrothermal method from coal fly ash. The synthesized catalysts were characterized by X-ray Diffraction (XRD), Scanning Electron Microscope (SEM), Energy Dispersive X-ray (EDX), and Thermogravimetric Analysis (TGA). The catalyst shows a crystalline structure with stability up to 900 °C. The catalytic performance analysis shows the CH4 conversion increases from 29 to 68% for 0 and 10 wt% Co over Zeolite-4A, respectively. The H2 selectivity was improved from 28–56% while CO selectivity increased from 24–52 % making H2/CO ratio > 1. The stability analysis shows the 10% Co/Zeolite-4A withstand for 24 h a time on stream (TOS). Finally, the spent catalyst analysis was carried out to check the carbon formation along with its structural analysis. The minimal carbon formation is analyzed in 24 h TOS for POM reaction. Copyright © 2021 by Authors, Published by BCREC Group. This is an open access article under the CC BY-SA License (https://creativecommons.org/licenses/by-sa/4.0).