Bis[2-(methylamino)troponato]copper(II)

Bis[2-(methylamino)troponato]copper(II)

In the title compound, [Cu(C8H8NO)2], a strictly square-planar geometry about the CuII metal atom is observed. Substitution of an O atom with a methyl-functionalized N atom does not significantly alter the bond distances and angles in the copper(II) complex when compared with a similar bis(troponato...

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Main Authors: Gideon Steyl, Andreas Roodt, Theunis J. Muller
Format: Article
Language:English
Published: International Union of Crystallography 2010-12-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536810043503
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spelling doaj-3100a6b45b834bc1bc871bfdabb886232020-11-25T00:31:14ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682010-12-016612m1508m150810.1107/S1600536810043503Bis[2-(methylamino)troponato]copper(II)Gideon SteylAndreas RoodtTheunis J. MullerIn the title compound, [Cu(C8H8NO)2], a strictly square-planar geometry about the CuII metal atom is observed. Substitution of an O atom with a methyl-functionalized N atom does not significantly alter the bond distances and angles in the copper(II) complex when compared with a similar bis(troponato)copper(II) complex. π–π stacking is observed between the tropolone rings, with interplanar distances of 3.5039 (16) and 3.2933 (15) Å, respectively. Additional stabilisation of the structure is accomplished through C—H...O hydrogen-bonding interactions. http://scripts.iucr.org/cgi-bin/paper?S1600536810043503
collection DOAJ
language English
format Article
sources DOAJ
author Gideon Steyl
Andreas Roodt
Theunis J. Muller
spellingShingle Gideon Steyl
Andreas Roodt
Theunis J. Muller
Bis[2-(methylamino)troponato]copper(II)
Acta Crystallographica Section E
author_facet Gideon Steyl
Andreas Roodt
Theunis J. Muller
author_sort Gideon Steyl
title Bis[2-(methylamino)troponato]copper(II)
title_short Bis[2-(methylamino)troponato]copper(II)
title_full Bis[2-(methylamino)troponato]copper(II)
title_fullStr Bis[2-(methylamino)troponato]copper(II)
title_full_unstemmed Bis[2-(methylamino)troponato]copper(II)
title_sort bis[2-(methylamino)troponato]copper(ii)
publisher International Union of Crystallography
series Acta Crystallographica Section E
issn 1600-5368
publishDate 2010-12-01
description In the title compound, [Cu(C8H8NO)2], a strictly square-planar geometry about the CuII metal atom is observed. Substitution of an O atom with a methyl-functionalized N atom does not significantly alter the bond distances and angles in the copper(II) complex when compared with a similar bis(troponato)copper(II) complex. π–π stacking is observed between the tropolone rings, with interplanar distances of 3.5039 (16) and 3.2933 (15) Å, respectively. Additional stabilisation of the structure is accomplished through C—H...O hydrogen-bonding interactions.
url http://scripts.iucr.org/cgi-bin/paper?S1600536810043503
work_keys_str_mv AT gideonsteyl bis2methylaminotroponatocopperii
AT andreasroodt bis2methylaminotroponatocopperii
AT theunisjmuller bis2methylaminotroponatocopperii
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