Bis(diphenylphosphorothioyl) trisulfide
In the title compound, C24H20P2S5, the P atoms are arranged trans with respect to the S3 group and the S=P—S—S systems have cisoid geometry, with an average S—P—S—S torsion angle of −56.7°. The dihedral angles between the two pheny...
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| Format: | Article |
| Language: | English |
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International Union of Crystallography
2008-09-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536808024070 |
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doaj-30b45736197a4d5ab19892c60d39a7442020-11-25T02:14:20ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682008-09-01649o1683o168410.1107/S1600536808024070Bis(diphenylphosphorothioyl) trisulfideMarius VonasAnca SilvestruMonika KulcsarIn the title compound, C24H20P2S5, the P atoms are arranged trans with respect to the S3 group and the S=P—S—S systems have cisoid geometry, with an average S—P—S—S torsion angle of −56.7°. The dihedral angles between the two phenyl rings attached to the P atoms are 87.33 (12) and 75.67 (10)°. In the crystal structure, the molecules are linked into chains running parallel to the a axis by weak intermolecular C—H...S hydrogen bonds. Centrosymmetrically related chains are further connected by π–π stacking interactions, with a centroid-to-centroid distance of 3.795 (5) Å.http://scripts.iucr.org/cgi-bin/paper?S1600536808024070 |
| collection |
DOAJ |
| language |
English |
| format |
Article |
| sources |
DOAJ |
| author |
Marius Vonas Anca Silvestru Monika Kulcsar |
| spellingShingle |
Marius Vonas Anca Silvestru Monika Kulcsar Bis(diphenylphosphorothioyl) trisulfide Acta Crystallographica Section E |
| author_facet |
Marius Vonas Anca Silvestru Monika Kulcsar |
| author_sort |
Marius Vonas |
| title |
Bis(diphenylphosphorothioyl) trisulfide |
| title_short |
Bis(diphenylphosphorothioyl) trisulfide |
| title_full |
Bis(diphenylphosphorothioyl) trisulfide |
| title_fullStr |
Bis(diphenylphosphorothioyl) trisulfide |
| title_full_unstemmed |
Bis(diphenylphosphorothioyl) trisulfide |
| title_sort |
bis(diphenylphosphorothioyl) trisulfide |
| publisher |
International Union of Crystallography |
| series |
Acta Crystallographica Section E |
| issn |
1600-5368 |
| publishDate |
2008-09-01 |
| description |
In the title compound, C24H20P2S5, the P atoms are arranged trans with respect to the S3 group and the S=P—S—S systems have cisoid geometry, with an average S—P—S—S torsion angle of −56.7°. The dihedral angles between the two phenyl rings attached to the P atoms are 87.33 (12) and 75.67 (10)°. In the crystal structure, the molecules are linked into chains running parallel to the a axis by weak intermolecular C—H...S hydrogen bonds. Centrosymmetrically related chains are further connected by π–π stacking interactions, with a centroid-to-centroid distance of 3.795 (5) Å. |
| url |
http://scripts.iucr.org/cgi-bin/paper?S1600536808024070 |
| work_keys_str_mv |
AT mariusvonas bisdiphenylphosphorothioyltrisulfide AT ancasilvestru bisdiphenylphosphorothioyltrisulfide AT monikakulcsar bisdiphenylphosphorothioyltrisulfide |
| _version_ |
1724900213641969664 |