Transparency anticorrosion coatings prepared from alumina-covered graphene oxide/polyimide nanocomposites

• Main Authors: G-H. Lai, T-C. Huang, I-H. Tseng, B-S. Huang, T-I. Yang, M-H. Tsai
• Format: Article
• Language: English
• Published: Budapest University of Technology 2019-09-01
• Series: eXPRESS Polymer Letters
• Subjects: Polymer composites; Polyimide; Alumina-covered graphene oxide; Anticorrosion
• Online Access: http://www.expresspolymlett.com/letolt.php?file=EPL-0009887&mi=cd

In this study, a novel alumina-covered graphene oxide/polyimide (AlGO/PI) nanocomposite was developed as an anticorrosion coating material. The hydroxyl groups on GO reacted with aluminum isopropoxide via a sol-gel process to yield AlGO nanosheets. The characterization and structure were confirmed by Fourier transform infrared spectrometry, X-ray photoelectron spectroscopy, field emission scanning electron microscopy, and field emission transmission electron microscopy. Subsequently, GO and AlGO were incorporated into a PI matrix, leading to the formation of GO/PI and AlGO/PI nanocomposites. Well-dispersed AlGO nanosheets in the PI matrix acted as effective additives to enhance the water barrier properties of GO/PI (58 g/(m2·day)) and AlGO/PI (43 g/(m2·day)) coatings. Most importantly, the resultant AlGO/PI films exhibited excellent optical transparency (>75%) and anticorrosion properties. Electrochemical measurements of corrosion potential, polarization resistance, and corrosion current as well as electrochemical impedance spectroscopy confirmed that the AlGO/PI nanocomposites exhibited better anticorrosion properties than GO/PI nanocomposites. This is likely because the insulating layer of alumina on GO can isolate the charge transfer pathway between GO and the metal substrates, leading to improved anticorrosion behavior.