Sonochemical Synthesis of a New Nano Lead(II) Coordination Polymer with 2,5-bis(2-pyridyl)-3,4-diaza-2,4- hexadiene ligand: A Precursor to Produce Pure Phase Nano- sized Lead(II) Oxide
A new nano-sized lead(II) coordination polymer, [Pb(2-bpdh)(NO3)2]n (1); (2-bpdh = 2,5-bis(2-pyridyl)-3,4-diaza-2,4-hexadiene)}, was synthesized by a sonochemical method. The structure of 1 may be considered coordination polymer of lead(II) consist of metallocyclicchains formed by bridging NO3- and...
| Main Authors: | , |
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| Format: | Article |
| Language: | English |
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Nanoscience and Nanotechnology Research Center, University of Kashan
2011-04-01
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| Series: | Journal of Nanostructures |
| Subjects: | |
| Online Access: | http://jns.kashanu.ac.ir/article_5248_34c9f24481c9d92c6127c07f57058ef0.pdf |
| Summary: | A new nano-sized lead(II) coordination polymer, [Pb(2-bpdh)(NO3)2]n (1); (2-bpdh = 2,5-bis(2-pyridyl)-3,4-diaza-2,4-hexadiene)}, was synthesized by a sonochemical method. The structure of 1 may be considered coordination polymer of lead(II) consist of metallocyclicchains formed by bridging NO3- and 2-bpdh ligands. The thermal stability of compound was studied by thermal gravimetric and differential thermal analyses. The new nano-structure coordination polymer was characterized by scanning electron microscopy, powder X-ray diffraction, elemental analyses and IR spectroscopy. The size of the samples was about 50 nm. Nano-particles of PbO were obtained by thermolysis of compound 1in oleic acid as a surfactant at 180 °C under air atmosphere and the size of this PbO particles were about 50 nm. |
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| ISSN: | 2251-7871 2251-788X |