(η2,η2-Cycloocta-1,5-diene)[2-(diphenylphosphanylmethyl)pyridine-κ2N,P]rhodium(I) tetrafluoridoborate 1,2-dichloroethane monosolvate

(η2,η2-Cycloocta-1,5-diene)[2-(diphenylphosphanylmethyl)pyridine-κ2N,P]rhodium(I) tetrafluoridoborate 1,2-dichloroethane monosolvate

The title compound, [Rh(C8H12)(C18H16NP)]BF4 has been prepared as a precatalyst for applications in rhodium-catalysed additions of carbocyclic acids to terminal alkynes leading to anti-Markovnikov Z-enol esters. Here the triclinic pseudopolymorph of the title compound is presented. In contrast to th...

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Bibliographic Details
Main Authors:	Siping Wei, Saskia Möller, Detlef Heller, Hans-Joachim Drexler
Format:	Article
Language:	English
Published:	International Union of Crystallography 2016-08-01
Series:	IUCrData
Subjects:	crystal structure polymorph rhodium complex
Online Access:	http://scripts.iucr.org/cgi-bin/paper?S2414314616013183

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