| Summary: | The study on the effect of material structure and solution properties on the streaming potential of the soil–rock mixture (SRM) will be beneficial for improving the reliability of the measurement results for self-potential monitoring in embankment dams. We design two experimental groups and investigate the changes of potential and pressure during seepage of SRM (slightly clay materials) with different compactness and different concentration. The effects of the compaction degree and solution concentration on the streaming potential coupling coefficient and streaming potential were analyzed. The test results demonstrate that when the clay content in soil matrix is slight, the potential has a linear relationship with the hydraulic head difference, and seepage obeys Darcy’s law. The surface conductivity is negligible at 0.01 M (1 M corresponds to a concentration of 58.4 g L<sup>−1</sup>) salinity, the compactness of the SRM decreases (the permeability coefficient increases), the apparent streaming potential coupling coefficient and pressure difference decrease is the reason streaming potential decreases. The permeability coefficient of the SRM is not affected by the change in salinity (0.0001–1 M) at 85% compactness, and its seepage characteristics are related to the mineral composition, morphology and the thickness of the bound water layer (electric double layer). This study lays a foundation for further research on the self-potential method to monitor the structure of embankment dams.
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