cis-Bis(4-methylpiperazine-1-carbodithioato-κ2S,S′)bis(pyridine-κN)cadmium

cis-Bis(4-methylpiperazine-1-carbodithioato-κ2S,S′)bis(pyridine-κN)cadmium

In the title complex, [Cd(C6H11N2S2)2(C5H5N)2], the CdII ion is hexacoordinated by two N atoms from two pyridine ligands and by four S atoms from two dithiocarbamate ligands in a distorted octahedral geometry. The CdII ion lies on a twofold axis. The piperazine ring is in chair conformation and its...

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Main Authors: P. Valarmathi, S. Thirumaran, Kamini Kapoor, Vivek K. Gupta, Rajni Kant
Format: Article
Language:English
Published: International Union of Crystallography 2012-01-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536811054791
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spelling doaj-2fdfa9f216134a6586412ff7dd2aeeea2020-11-25T03:36:25ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682012-01-01681m89m8910.1107/S1600536811054791cis-Bis(4-methylpiperazine-1-carbodithioato-κ2S,S′)bis(pyridine-κN)cadmiumP. ValarmathiS. ThirumaranKamini KapoorVivek K. GuptaRajni KantIn the title complex, [Cd(C6H11N2S2)2(C5H5N)2], the CdII ion is hexacoordinated by two N atoms from two pyridine ligands and by four S atoms from two dithiocarbamate ligands in a distorted octahedral geometry. The CdII ion lies on a twofold axis. The piperazine ring is in chair conformation and its least-squares plane makes a dihedral angle of 81.4 (1)° with that of the pyridine ring.http://scripts.iucr.org/cgi-bin/paper?S1600536811054791
collection DOAJ
language English
format Article
sources DOAJ
author P. Valarmathi
S. Thirumaran
Kamini Kapoor
Vivek K. Gupta
Rajni Kant
spellingShingle P. Valarmathi
S. Thirumaran
Kamini Kapoor
Vivek K. Gupta
Rajni Kant
cis-Bis(4-methylpiperazine-1-carbodithioato-κ2S,S′)bis(pyridine-κN)cadmium
Acta Crystallographica Section E
author_facet P. Valarmathi
S. Thirumaran
Kamini Kapoor
Vivek K. Gupta
Rajni Kant
author_sort P. Valarmathi
title cis-Bis(4-methylpiperazine-1-carbodithioato-κ2S,S′)bis(pyridine-κN)cadmium
title_short cis-Bis(4-methylpiperazine-1-carbodithioato-κ2S,S′)bis(pyridine-κN)cadmium
title_full cis-Bis(4-methylpiperazine-1-carbodithioato-κ2S,S′)bis(pyridine-κN)cadmium
title_fullStr cis-Bis(4-methylpiperazine-1-carbodithioato-κ2S,S′)bis(pyridine-κN)cadmium
title_full_unstemmed cis-Bis(4-methylpiperazine-1-carbodithioato-κ2S,S′)bis(pyridine-κN)cadmium
title_sort cis-bis(4-methylpiperazine-1-carbodithioato-κ2s,s′)bis(pyridine-κn)cadmium
publisher International Union of Crystallography
series Acta Crystallographica Section E
issn 1600-5368
publishDate 2012-01-01
description In the title complex, [Cd(C6H11N2S2)2(C5H5N)2], the CdII ion is hexacoordinated by two N atoms from two pyridine ligands and by four S atoms from two dithiocarbamate ligands in a distorted octahedral geometry. The CdII ion lies on a twofold axis. The piperazine ring is in chair conformation and its least-squares plane makes a dihedral angle of 81.4 (1)° with that of the pyridine ring.
url http://scripts.iucr.org/cgi-bin/paper?S1600536811054791
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AT sthirumaran cisbis4methylpiperazine1carbodithioatoamp9542ssamp8242bispyridineamp954ncadmium
AT kaminikapoor cisbis4methylpiperazine1carbodithioatoamp9542ssamp8242bispyridineamp954ncadmium
AT vivekkgupta cisbis4methylpiperazine1carbodithioatoamp9542ssamp8242bispyridineamp954ncadmium
AT rajnikant cisbis4methylpiperazine1carbodithioatoamp9542ssamp8242bispyridineamp954ncadmium
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