Characterization of Flowpath Using Geochemistry and <sup>87</sup>Sr/<sup>86</sup>Sr Isotope Ratios in the Yalahau Region, Yucatan Peninsula, Mexico

The Yalahau region, located in the northeastern portion of the Yucatán Peninsula, hosts a series of elongated depressions trending north/south in the direction of Isla Holbox, identified as the Holbox Fracture Zone. Previous studies have explored the geomorphology and various hydrologic characterist...

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Main Authors: Jessica McKay, Melissa Lenczewski, Rosa Maria Leal-Bautista
Format: Article
Language:English
Published: MDPI AG 2020-09-01
Series:Water
Subjects:
Online Access:https://www.mdpi.com/2073-4441/12/9/2587
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spelling doaj-2fa1784b46124706a76ea32685a7c0f62020-11-25T03:41:47ZengMDPI AGWater2073-44412020-09-01122587258710.3390/w12092587Characterization of Flowpath Using Geochemistry and <sup>87</sup>Sr/<sup>86</sup>Sr Isotope Ratios in the Yalahau Region, Yucatan Peninsula, MexicoJessica McKay0Melissa Lenczewski1Rosa Maria Leal-Bautista2Department of Geology and Environmental Geosciences DeKalb, Northern Illinois University, DeKalb, IL 60115, USADepartment of Geology and Environmental Geosciences DeKalb, Northern Illinois University, DeKalb, IL 60115, USACentro de Investigacion Cientifica de Yucatan, Unidad de Ciencias del Agua, Cancun, Quintana Roo 77524, MexicoThe Yalahau region, located in the northeastern portion of the Yucatán Peninsula, hosts a series of elongated depressions trending north/south in the direction of Isla Holbox, identified as the Holbox Fracture Zone. Previous studies have explored the geomorphology and various hydrologic characteristics of the Yucatán Peninsula; however, there is a paucity of data concerning the interior region where the fractures are located. Strontium isotope ratios and major ion geochemistry data of the surface water and groundwater of this region serve as a hydrogeochemical fingerprint, aiding in constraining the hydrological boundaries, determining flow paths, and characterizing hydrogeochemical processes that impact the composition of the groundwater within the region. <sup>87</sup>Sr/<sup>86</sup>Sr isotope ratios indicate a different signature than the surrounding bedrock Sr ratio, suggesting that the flow throughout the Yalahau region is moving through channels faster than that of much of the Yucatán. Through major ion geochemistry and <sup>87</sup>Sr/<sup>86</sup>Sr isotope ratios, we were able to delineate at least two flow paths within the Yalahau region and identify a point of saline intrusion at least 35 km from the coast. Gaining an understanding of the hydrogeochemistry and water flow regions is crucial in determining the impact of various activities (e.g., extensive tourism, drinking water withdrawal, wastewater discharge/injection) that occur within the Yucatán Peninsula.https://www.mdpi.com/2073-4441/12/9/2587geochemistry<sup>87</sup>Sr/<sup>86</sup>Sr isotope ratiosflow pathYucatan Peninsula
collection DOAJ
language English
format Article
sources DOAJ
author Jessica McKay
Melissa Lenczewski
Rosa Maria Leal-Bautista
spellingShingle Jessica McKay
Melissa Lenczewski
Rosa Maria Leal-Bautista
Characterization of Flowpath Using Geochemistry and <sup>87</sup>Sr/<sup>86</sup>Sr Isotope Ratios in the Yalahau Region, Yucatan Peninsula, Mexico
Water
geochemistry
<sup>87</sup>Sr/<sup>86</sup>Sr isotope ratios
flow path
Yucatan Peninsula
author_facet Jessica McKay
Melissa Lenczewski
Rosa Maria Leal-Bautista
author_sort Jessica McKay
title Characterization of Flowpath Using Geochemistry and <sup>87</sup>Sr/<sup>86</sup>Sr Isotope Ratios in the Yalahau Region, Yucatan Peninsula, Mexico
title_short Characterization of Flowpath Using Geochemistry and <sup>87</sup>Sr/<sup>86</sup>Sr Isotope Ratios in the Yalahau Region, Yucatan Peninsula, Mexico
title_full Characterization of Flowpath Using Geochemistry and <sup>87</sup>Sr/<sup>86</sup>Sr Isotope Ratios in the Yalahau Region, Yucatan Peninsula, Mexico
title_fullStr Characterization of Flowpath Using Geochemistry and <sup>87</sup>Sr/<sup>86</sup>Sr Isotope Ratios in the Yalahau Region, Yucatan Peninsula, Mexico
title_full_unstemmed Characterization of Flowpath Using Geochemistry and <sup>87</sup>Sr/<sup>86</sup>Sr Isotope Ratios in the Yalahau Region, Yucatan Peninsula, Mexico
title_sort characterization of flowpath using geochemistry and <sup>87</sup>sr/<sup>86</sup>sr isotope ratios in the yalahau region, yucatan peninsula, mexico
publisher MDPI AG
series Water
issn 2073-4441
publishDate 2020-09-01
description The Yalahau region, located in the northeastern portion of the Yucatán Peninsula, hosts a series of elongated depressions trending north/south in the direction of Isla Holbox, identified as the Holbox Fracture Zone. Previous studies have explored the geomorphology and various hydrologic characteristics of the Yucatán Peninsula; however, there is a paucity of data concerning the interior region where the fractures are located. Strontium isotope ratios and major ion geochemistry data of the surface water and groundwater of this region serve as a hydrogeochemical fingerprint, aiding in constraining the hydrological boundaries, determining flow paths, and characterizing hydrogeochemical processes that impact the composition of the groundwater within the region. <sup>87</sup>Sr/<sup>86</sup>Sr isotope ratios indicate a different signature than the surrounding bedrock Sr ratio, suggesting that the flow throughout the Yalahau region is moving through channels faster than that of much of the Yucatán. Through major ion geochemistry and <sup>87</sup>Sr/<sup>86</sup>Sr isotope ratios, we were able to delineate at least two flow paths within the Yalahau region and identify a point of saline intrusion at least 35 km from the coast. Gaining an understanding of the hydrogeochemistry and water flow regions is crucial in determining the impact of various activities (e.g., extensive tourism, drinking water withdrawal, wastewater discharge/injection) that occur within the Yucatán Peninsula.
topic geochemistry
<sup>87</sup>Sr/<sup>86</sup>Sr isotope ratios
flow path
Yucatan Peninsula
url https://www.mdpi.com/2073-4441/12/9/2587
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