4,6-Di-tert-butyl-2-({[4-(diethylamino)phenyl]imino}methyl)phenol

4,6-Di-tert-butyl-2-({[4-(diethylamino)phenyl]imino}methyl)phenol

The title compound, C25H36N2O, adopts an E conformation about the C=N bond. The dihedral angle between the aromatic rings is 35.6 (6)°. The molecular structure is stabilized by an O—H...N hydrogen bond, which forms an S(6) loop, and weak C—H...O contacts. Weak intermolecular C—H...π interactions are...

Full description

Bibliographic Details
Main Authors: C. Vidya Rani, L. Mitu, G. Chakkaravarthi, G. Rajagopal
Format: Article
Language:English
Published: International Union of Crystallography 2017-04-01
Series:IUCrData
Subjects:
crystal structure
disordered diethylamine moiety
hydrogen bonding
Online Access:http://scripts.iucr.org/cgi-bin/paper?S2414314617005727
id doaj-2f653dba2c814023829f7d7ff976e147
record_format Article
spelling doaj-2f653dba2c814023829f7d7ff976e1472020-11-24T23:46:54ZengInternational Union of CrystallographyIUCrData2414-31462017-04-0124x17057210.1107/S2414314617005727vm40224,6-Di-tert-butyl-2-({[4-(diethylamino)phenyl]imino}methyl)phenolC. Vidya Rani0L. Mitu1G. Chakkaravarthi2G. Rajagopal3Department of Chemistry, Vaigai College of Engineering, Madurai 625 122, Tamil Nadu, IndiaDepartment of Chemistry, University of Pitesti, Pitesti 11040, RomaniaDepartment of Physics, CPCL Polytechnic College, Chennai 600 068, IndiaPG & Research Department of Chemistry, Chikkanna Government Arts College, Tiruppur 641 602, Tamil Nadu, IndiaThe title compound, C25H36N2O, adopts an E conformation about the C=N bond. The dihedral angle between the aromatic rings is 35.6 (6)°. The molecular structure is stabilized by an O—H...N hydrogen bond, which forms an S(6) loop, and weak C—H...O contacts. Weak intermolecular C—H...π interactions are observed in the crystal packing. The diethylamino group has rotational disorder with site occupancies of 0.85 (2) and 0.15 (2) for the major and minor components, respectively. The structure was refined as a three-component twin.http://scripts.iucr.org/cgi-bin/paper?S2414314617005727crystal structuredisordered diethylamine moietyhydrogen bonding
collection DOAJ
language English
format Article
sources DOAJ
author C. Vidya Rani
L. Mitu
G. Chakkaravarthi
G. Rajagopal
spellingShingle C. Vidya Rani
L. Mitu
G. Chakkaravarthi
G. Rajagopal
4,6-Di-tert-butyl-2-({[4-(diethylamino)phenyl]imino}methyl)phenol
IUCrData
crystal structure
disordered diethylamine moiety
hydrogen bonding
author_facet C. Vidya Rani
L. Mitu
G. Chakkaravarthi
G. Rajagopal
author_sort C. Vidya Rani
title 4,6-Di-tert-butyl-2-({[4-(diethylamino)phenyl]imino}methyl)phenol
title_short 4,6-Di-tert-butyl-2-({[4-(diethylamino)phenyl]imino}methyl)phenol
title_full 4,6-Di-tert-butyl-2-({[4-(diethylamino)phenyl]imino}methyl)phenol
title_fullStr 4,6-Di-tert-butyl-2-({[4-(diethylamino)phenyl]imino}methyl)phenol
title_full_unstemmed 4,6-Di-tert-butyl-2-({[4-(diethylamino)phenyl]imino}methyl)phenol
title_sort 4,6-di-tert-butyl-2-({[4-(diethylamino)phenyl]imino}methyl)phenol
publisher International Union of Crystallography
series IUCrData
issn 2414-3146
publishDate 2017-04-01
description The title compound, C25H36N2O, adopts an E conformation about the C=N bond. The dihedral angle between the aromatic rings is 35.6 (6)°. The molecular structure is stabilized by an O—H...N hydrogen bond, which forms an S(6) loop, and weak C—H...O contacts. Weak intermolecular C—H...π interactions are observed in the crystal packing. The diethylamino group has rotational disorder with site occupancies of 0.85 (2) and 0.15 (2) for the major and minor components, respectively. The structure was refined as a three-component twin.
topic crystal structure
disordered diethylamine moiety
hydrogen bonding
url http://scripts.iucr.org/cgi-bin/paper?S2414314617005727
work_keys_str_mv AT cvidyarani 46ditertbutyl24diethylaminophenyliminomethylphenol
AT lmitu 46ditertbutyl24diethylaminophenyliminomethylphenol
AT gchakkaravarthi 46ditertbutyl24diethylaminophenyliminomethylphenol
AT grajagopal 46ditertbutyl24diethylaminophenyliminomethylphenol
_version_ 1725491761185292288

Similar Items