(R)-2-{2-[(S)-(2′-Benzoyloxy-1,1′-binaphthyl-2-yl)oxycarbonylamino]-3-phenylpropanamidomethyl}pyridinium picrate acetone solvate

(R)-2-{2-[(S)-(2′-Benzoyloxy-1,1′-binaphthyl-2-yl)oxycarbonylamino]-3-phenylpropanamidomethyl}pyridinium picrate acetone solvate

In the crystal structure of the title compound, C43H34N3O5+·C6H2N3O7−·C3H6O, the large dimension and shape of the cation are responsible for the elongation of the orthorhombic unit cell. The ions and acetone molecules are linked together by a system of hydrogen bonds invo...

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Main Authors: Ludvík Streinz, Petr Hartvich, Jan Ondráček, Petr Šimek, Michal Dušek, Karla Fejfarová
Format: Article
Language:English
Published: International Union of Crystallography 2008-01-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S160053680706669X
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spelling doaj-2f2f3dd4bc0c47369a6ec8ba1563c4662020-11-25T00:12:43ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682008-01-01641o326o32710.1107/S160053680706669X(R)-2-{2-[(S)-(2′-Benzoyloxy-1,1′-binaphthyl-2-yl)oxycarbonylamino]-3-phenylpropanamidomethyl}pyridinium picrate acetone solvateLudvík StreinzPetr HartvichJan OndráčekPetr ŠimekMichal DušekKarla FejfarováIn the crystal structure of the title compound, C43H34N3O5+·C6H2N3O7−·C3H6O, the large dimension and shape of the cation are responsible for the elongation of the orthorhombic unit cell. The ions and acetone molecules are linked together by a system of hydrogen bonds involving an intermolecular hydrogen bond between one N atom of the cation and the O atom of acetone and two intermolecular hydrogen bonds between the cation N atoms and the O atoms of the picrate anion. No intramolecular hydrogen bonds exist in the structure. The dihedral angle between the two naphthalene ring systems is 76.16 (13)°. The chiral C atom has a known R configuration, but this cannot be confirmed from this X-ray analysis.http://scripts.iucr.org/cgi-bin/paper?S160053680706669X
collection DOAJ
language English
format Article
sources DOAJ
author Ludvík Streinz
Petr Hartvich
Jan Ondráček
Petr Šimek
Michal Dušek
Karla Fejfarová
spellingShingle Ludvík Streinz
Petr Hartvich
Jan Ondráček
Petr Šimek
Michal Dušek
Karla Fejfarová
(R)-2-{2-[(S)-(2′-Benzoyloxy-1,1′-binaphthyl-2-yl)oxycarbonylamino]-3-phenylpropanamidomethyl}pyridinium picrate acetone solvate
Acta Crystallographica Section E
author_facet Ludvík Streinz
Petr Hartvich
Jan Ondráček
Petr Šimek
Michal Dušek
Karla Fejfarová
author_sort Ludvík Streinz
title (R)-2-{2-[(S)-(2′-Benzoyloxy-1,1′-binaphthyl-2-yl)oxycarbonylamino]-3-phenylpropanamidomethyl}pyridinium picrate acetone solvate
title_short (R)-2-{2-[(S)-(2′-Benzoyloxy-1,1′-binaphthyl-2-yl)oxycarbonylamino]-3-phenylpropanamidomethyl}pyridinium picrate acetone solvate
title_full (R)-2-{2-[(S)-(2′-Benzoyloxy-1,1′-binaphthyl-2-yl)oxycarbonylamino]-3-phenylpropanamidomethyl}pyridinium picrate acetone solvate
title_fullStr (R)-2-{2-[(S)-(2′-Benzoyloxy-1,1′-binaphthyl-2-yl)oxycarbonylamino]-3-phenylpropanamidomethyl}pyridinium picrate acetone solvate
title_full_unstemmed (R)-2-{2-[(S)-(2′-Benzoyloxy-1,1′-binaphthyl-2-yl)oxycarbonylamino]-3-phenylpropanamidomethyl}pyridinium picrate acetone solvate
title_sort (r)-2-{2-[(s)-(2′-benzoyloxy-1,1′-binaphthyl-2-yl)oxycarbonylamino]-3-phenylpropanamidomethyl}pyridinium picrate acetone solvate
publisher International Union of Crystallography
series Acta Crystallographica Section E
issn 1600-5368
publishDate 2008-01-01
description In the crystal structure of the title compound, C43H34N3O5+·C6H2N3O7−·C3H6O, the large dimension and shape of the cation are responsible for the elongation of the orthorhombic unit cell. The ions and acetone molecules are linked together by a system of hydrogen bonds involving an intermolecular hydrogen bond between one N atom of the cation and the O atom of acetone and two intermolecular hydrogen bonds between the cation N atoms and the O atoms of the picrate anion. No intramolecular hydrogen bonds exist in the structure. The dihedral angle between the two naphthalene ring systems is 76.16 (13)°. The chiral C atom has a known R configuration, but this cannot be confirmed from this X-ray analysis.
url http://scripts.iucr.org/cgi-bin/paper?S160053680706669X
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AT petrhartvich r22s28242benzoyloxy118242binaphthyl2yloxycarbonylamino3phenylpropanamidomethylpyridiniumpicrateacetonesolvate
AT janondr225269ek r22s28242benzoyloxy118242binaphthyl2yloxycarbonylamino3phenylpropanamidomethylpyridiniumpicrateacetonesolvate
AT petr352imek r22s28242benzoyloxy118242binaphthyl2yloxycarbonylamino3phenylpropanamidomethylpyridiniumpicrateacetonesolvate
AT michaldu353ek r22s28242benzoyloxy118242binaphthyl2yloxycarbonylamino3phenylpropanamidomethylpyridiniumpicrateacetonesolvate
AT karlafejfarov225 r22s28242benzoyloxy118242binaphthyl2yloxycarbonylamino3phenylpropanamidomethylpyridiniumpicrateacetonesolvate
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