μ-Decanedioato-bis[aquabis(1,10-phenanthroline-κ2N,N′)manganese(II)] dinitrate–sebacic acid–water (1/1/2)

μ-Decanedioato-bis[aquabis(1,10-phenanthroline-κ2N,N′)manganese(II)] dinitrate–sebacic acid–water (1/1/2)

In the title complex, [Mn2(C10H16O4)(C12H8N2)4(H2O)2](NO3)2·C10H18O4·2H2O, the asymmetric unit contains one-half of the centrosymmetric dinuclear complex cation, one uncoordinated water molecule, one-half of a free sebaic acid (decanedioic acid) molecule that is also comple...

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Bibliographic Details
Main Authors: Juan Li, Jian Long, Ye-Qiang Feng
Format: Article
Language:English
Published: International Union of Crystallography 2011-01-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536810051615
Description
Summary:In the title complex, [Mn2(C10H16O4)(C12H8N2)4(H2O)2](NO3)2·C10H18O4·2H2O, the asymmetric unit contains one-half of the centrosymmetric dinuclear complex cation, one uncoordinated water molecule, one-half of a free sebaic acid (decanedioic acid) molecule that is also completed by inversion symmetry, and one disordered nitrate anion [occupancy ratio 0.454 (4):0.544 (6)]. The MnII atoms are each octahedrally surrounded by four N atoms from two 1,10-phenanthroline (phen) ligands, one O atom from one carbonyl group of the bridging sebacate ligand and one O atom of a water molecule. The crystal structure is stabilized by intermolecular O—H...O hydrogen bonds.
ISSN:1600-5368

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