4-Fluoroanilinium tetrachloridoferrate(III) 18-crown-6 clathrate
The reaction of 4-fluoroaniline hydrochloride, 18-crown-6 and ferric chloride in methanolic solution yields the title compound, (C6H7FN)[FeCl4]·C12H24O6, which has an unusual supramolecular structure. N—H...O hydrogen-bonding interactions between the NH3+ substituents of t...
| Main Authors: | , |
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| Format: | Article |
| Language: | English |
| Published: |
International Union of Crystallography
2010-07-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S160053681002009X |
| Summary: | The reaction of 4-fluoroaniline hydrochloride, 18-crown-6 and ferric chloride in methanolic solution yields the title compound, (C6H7FN)[FeCl4]·C12H24O6, which has an unusual supramolecular structure. N—H...O hydrogen-bonding interactions between the NH3+ substituents of the 4-fluoroanilinium cations and the O atoms of the crown ether molecules result in a rotator–stator-like structure. |
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| ISSN: | 1600-5368 |