catena-Poly[diimidazolium [bis(μ-pyridine-2,5-dicarboxylato)bis[diaquapraseodymate(III)]]-bis(μ-pyridine-2,5-dicarboxylato)]

catena-Poly[diimidazolium [bis(μ-pyridine-2,5-dicarboxylato)bis[diaquapraseodymate(III)]]-bis(μ-pyridine-2,5-dicarboxylato)]

The title compound {(C3H5N2)2[Pr2(C7H3NO4)4(H2O)4]}n, has a chain structure featuring a dimeric unit consisting of two PrIII atoms within a dodecahedral environment. Each of the metal cations is coordinated by two N atoms and two O atoms from two pyridine-2,5-dicarboxylate ligands, two O atoms from...

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Main Authors: Wenjun Zhang, Yanmei Chen, Tao Lei, Yahong Li, Wu Li
Format: Article
Language:English
Published: International Union of Crystallography 2011-05-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536811012360
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spelling doaj-2e92d61c1ea04c798800e7efc244e7de2020-11-25T00:50:21ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682011-05-01675m569m57010.1107/S1600536811012360catena-Poly[diimidazolium [bis(μ-pyridine-2,5-dicarboxylato)bis[diaquapraseodymate(III)]]-bis(μ-pyridine-2,5-dicarboxylato)]Wenjun ZhangYanmei ChenTao LeiYahong LiWu LiThe title compound {(C3H5N2)2[Pr2(C7H3NO4)4(H2O)4]}n, has a chain structure featuring a dimeric unit consisting of two PrIII atoms within a dodecahedral environment. Each of the metal cations is coordinated by two N atoms and two O atoms from two pyridine-2,5-dicarboxylate ligands, two O atoms from another two pyridine-2,5-dicarboxylate ligands and two water O atoms. The PrIII ions are bridged by two ligands along the c axis, forming the dimeric unit, and these are connected by four ligands along the b axis, forming a chain. N—H...O and O—H...O hydrogen bonds are found in the structure.http://scripts.iucr.org/cgi-bin/paper?S1600536811012360
collection DOAJ
language English
format Article
sources DOAJ
author Wenjun Zhang
Yanmei Chen
Tao Lei
Yahong Li
Wu Li
spellingShingle Wenjun Zhang
Yanmei Chen
Tao Lei
Yahong Li
Wu Li
catena-Poly[diimidazolium [bis(μ-pyridine-2,5-dicarboxylato)bis[diaquapraseodymate(III)]]-bis(μ-pyridine-2,5-dicarboxylato)]
Acta Crystallographica Section E
author_facet Wenjun Zhang
Yanmei Chen
Tao Lei
Yahong Li
Wu Li
author_sort Wenjun Zhang
title catena-Poly[diimidazolium [bis(μ-pyridine-2,5-dicarboxylato)bis[diaquapraseodymate(III)]]-bis(μ-pyridine-2,5-dicarboxylato)]
title_short catena-Poly[diimidazolium [bis(μ-pyridine-2,5-dicarboxylato)bis[diaquapraseodymate(III)]]-bis(μ-pyridine-2,5-dicarboxylato)]
title_full catena-Poly[diimidazolium [bis(μ-pyridine-2,5-dicarboxylato)bis[diaquapraseodymate(III)]]-bis(μ-pyridine-2,5-dicarboxylato)]
title_fullStr catena-Poly[diimidazolium [bis(μ-pyridine-2,5-dicarboxylato)bis[diaquapraseodymate(III)]]-bis(μ-pyridine-2,5-dicarboxylato)]
title_full_unstemmed catena-Poly[diimidazolium [bis(μ-pyridine-2,5-dicarboxylato)bis[diaquapraseodymate(III)]]-bis(μ-pyridine-2,5-dicarboxylato)]
title_sort catena-poly[diimidazolium [bis(μ-pyridine-2,5-dicarboxylato)bis[diaquapraseodymate(iii)]]-bis(μ-pyridine-2,5-dicarboxylato)]
publisher International Union of Crystallography
series Acta Crystallographica Section E
issn 1600-5368
publishDate 2011-05-01
description The title compound {(C3H5N2)2[Pr2(C7H3NO4)4(H2O)4]}n, has a chain structure featuring a dimeric unit consisting of two PrIII atoms within a dodecahedral environment. Each of the metal cations is coordinated by two N atoms and two O atoms from two pyridine-2,5-dicarboxylate ligands, two O atoms from another two pyridine-2,5-dicarboxylate ligands and two water O atoms. The PrIII ions are bridged by two ligands along the c axis, forming the dimeric unit, and these are connected by four ligands along the b axis, forming a chain. N—H...O and O—H...O hydrogen bonds are found in the structure.
url http://scripts.iucr.org/cgi-bin/paper?S1600536811012360
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AT yanmeichen catenapolydiimidazoliumbisamp956pyridine25dicarboxylatobisdiaquapraseodymateiiibisamp956pyridine25dicarboxylato
AT taolei catenapolydiimidazoliumbisamp956pyridine25dicarboxylatobisdiaquapraseodymateiiibisamp956pyridine25dicarboxylato
AT yahongli catenapolydiimidazoliumbisamp956pyridine25dicarboxylatobisdiaquapraseodymateiiibisamp956pyridine25dicarboxylato
AT wuli catenapolydiimidazoliumbisamp956pyridine25dicarboxylatobisdiaquapraseodymateiiibisamp956pyridine25dicarboxylato
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