Aqua(2,2′-bipyridyl)(pyrazine-2,6-dicarboxylato)nickel(II) 1.25-hydrate
The asymmetric unit of the title compound, [Ni(C6H2N2O4)(C10H8N2)(H2O)]·1.25H2O, contains two independent chemically identical NiII complex cations and two and a half solvent water molecules. The NiII ions are in slightly distorted coordination environments. In the crystal structure, interm...
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International Union of Crystallography
2008-11-01
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Series: | Acta Crystallographica Section E |
Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536808034806 |
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doaj-2e9247d08d9d48d4a08debd1eb3d64262020-11-25T01:22:57ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682008-11-016411m1480m148110.1107/S1600536808034806Aqua(2,2′-bipyridyl)(pyrazine-2,6-dicarboxylato)nickel(II) 1.25-hydrateYuan-Fang ZhangFeng-Qin WangThe asymmetric unit of the title compound, [Ni(C6H2N2O4)(C10H8N2)(H2O)]·1.25H2O, contains two independent chemically identical NiII complex cations and two and a half solvent water molecules. The NiII ions are in slightly distorted coordination environments. In the crystal structure, intermolecular O—H...O and weak C—H...O hydrogen bonds link cations and water molecules into a three-dimensional network. One of the three uncoordinated water molecules is half-occupied.http://scripts.iucr.org/cgi-bin/paper?S1600536808034806 |
collection |
DOAJ |
language |
English |
format |
Article |
sources |
DOAJ |
author |
Yuan-Fang Zhang Feng-Qin Wang |
spellingShingle |
Yuan-Fang Zhang Feng-Qin Wang Aqua(2,2′-bipyridyl)(pyrazine-2,6-dicarboxylato)nickel(II) 1.25-hydrate Acta Crystallographica Section E |
author_facet |
Yuan-Fang Zhang Feng-Qin Wang |
author_sort |
Yuan-Fang Zhang |
title |
Aqua(2,2′-bipyridyl)(pyrazine-2,6-dicarboxylato)nickel(II) 1.25-hydrate |
title_short |
Aqua(2,2′-bipyridyl)(pyrazine-2,6-dicarboxylato)nickel(II) 1.25-hydrate |
title_full |
Aqua(2,2′-bipyridyl)(pyrazine-2,6-dicarboxylato)nickel(II) 1.25-hydrate |
title_fullStr |
Aqua(2,2′-bipyridyl)(pyrazine-2,6-dicarboxylato)nickel(II) 1.25-hydrate |
title_full_unstemmed |
Aqua(2,2′-bipyridyl)(pyrazine-2,6-dicarboxylato)nickel(II) 1.25-hydrate |
title_sort |
aqua(2,2′-bipyridyl)(pyrazine-2,6-dicarboxylato)nickel(ii) 1.25-hydrate |
publisher |
International Union of Crystallography |
series |
Acta Crystallographica Section E |
issn |
1600-5368 |
publishDate |
2008-11-01 |
description |
The asymmetric unit of the title compound, [Ni(C6H2N2O4)(C10H8N2)(H2O)]·1.25H2O, contains two independent chemically identical NiII complex cations and two and a half solvent water molecules. The NiII ions are in slightly distorted coordination environments. In the crystal structure, intermolecular O—H...O and weak C—H...O hydrogen bonds link cations and water molecules into a three-dimensional network. One of the three uncoordinated water molecules is half-occupied. |
url |
http://scripts.iucr.org/cgi-bin/paper?S1600536808034806 |
work_keys_str_mv |
AT yuanfangzhang aqua228242bipyridylpyrazine26dicarboxylatonickelii125hydrate AT fengqinwang aqua228242bipyridylpyrazine26dicarboxylatonickelii125hydrate |
_version_ |
1725124502160932864 |