Use of metallurgical dust for removal chromium ions from aqueous solutions

The aim of the study was to determine the potential for the application of dust from steel plant as an effective sorbent for removing Cr(III) and Cr(VI) in the form of simple and complex ions – Acid Blue 193 dye from aqueous solutions. Three isotherms models were used to interpret the experimental r...

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Bibliographic Details
Main Authors: Pająk Magdalena, Dzieniszewska Agnieszka, Kyzioł-Komosińska Joanna, Chrobok Michał
Format: Article
Language:English
Published: EDP Sciences 2018-01-01
Series:E3S Web of Conferences
Online Access:https://doi.org/10.1051/e3sconf/20182801029
Description
Summary:The aim of the study was to determine the potential for the application of dust from steel plant as an effective sorbent for removing Cr(III) and Cr(VI) in the form of simple and complex ions – Acid Blue 193 dye from aqueous solutions. Three isotherms models were used to interpret the experimental results namely: Langmuir, Freundlich, and Dubinin–Radushkevich. Estimated equations parameters allowed to determine the binding mechanism. Based on laboratory studies it was found that the dust was characterized by high sorption capacities for Cr ions and dye from the aqueous solution. The sorption capacity of the dust for Cr(III) and Cr(VI) ions depended on the degree of oxidation, pH of solution and kind of anion and changed in series: Cr(III)-Cl pH=5.0> Cr(III)-SO4 pH=5.0> Cr(III)-Cl pH=3.0> Cr(III)-SO4 pH=3.0> Cr(VI) pH=5.0> Cr(VI) pH=3.0. Dust was also characterized by a high maximum sorption capacity of dye at a range of 38.2 – 91.7 mg/g, depending on the dose of dust. Based on the study it was found that dust from a steel plant, containing iron oxides, can be used as low-cost and effective sorbent to remove pollutions containing chromium ions, especially from acidic wastewater.
ISSN:2267-1242