N-BUTYL SUBSTITUTED N-HETEROCYCLIC CARBENE-PD(II)-PYRIDINE (PEPPSI) COMPLEXES: SYNTHESIS, CHARACTERIZATION AND CATALYTIC ACTIVITY IN THE SUZUKI-MIYAURA REACTION

N-BUTYL SUBSTITUTED N-HETEROCYCLIC CARBENE-PD(II)-PYRIDINE (PEPPSI) COMPLEXES: SYNTHESIS, CHARACTERIZATION AND CATALYTIC ACTIVITY IN THE SUZUKI-MIYAURA REACTION

A series of N-butyl substituted imidazolium salts, (1a-c) and their pyridine enhanced precatalyst preparation stabilization and initiation (PEPPSI) themed palladium N-heterocyclic carbene complexes (2a-c) were synthesized and characterized. Pd-NHC complexes were fully determined by elemental analysi...

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Main Author: Rukiye Fırıncı
Format: Article
Language:English
Published: Turkish Chemical Society 2016-08-01
Series:Journal of the Turkish Chemical Society, Section A: Chemistry
Online Access:http://dergipark.gov.tr/jotcsa/issue/27290/287258?publisher=turchemsoc
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spelling doaj-2e43d0b248d045df826f17d03ce0e1d92020-11-25T00:35:03ZengTurkish Chemical SocietyJournal of the Turkish Chemical Society, Section A: Chemistry2149-01202016-08-01339310410.18596/jotcsa.90024182N-BUTYL SUBSTITUTED N-HETEROCYCLIC CARBENE-PD(II)-PYRIDINE (PEPPSI) COMPLEXES: SYNTHESIS, CHARACTERIZATION AND CATALYTIC ACTIVITY IN THE SUZUKI-MIYAURA REACTIONRukiye FırıncıA series of N-butyl substituted imidazolium salts, (1a-c) and their pyridine enhanced precatalyst preparation stabilization and initiation (PEPPSI) themed palladium N-heterocyclic carbene complexes (2a-c) were synthesized and characterized. Pd-NHC complexes were fully determined by elemental analysis and spectroscopic. The synthesized complexes were tested in Suzuki-Miyaura cross-coupling reaction. These complexes were found to be efficient catalysts for the Suzuki-Miyaura reaction of phenylboronic acid with aryl bromides.http://dergipark.gov.tr/jotcsa/issue/27290/287258?publisher=turchemsoc
collection DOAJ
language English
format Article
sources DOAJ
author Rukiye Fırıncı
spellingShingle Rukiye Fırıncı
N-BUTYL SUBSTITUTED N-HETEROCYCLIC CARBENE-PD(II)-PYRIDINE (PEPPSI) COMPLEXES: SYNTHESIS, CHARACTERIZATION AND CATALYTIC ACTIVITY IN THE SUZUKI-MIYAURA REACTION
Journal of the Turkish Chemical Society, Section A: Chemistry
author_facet Rukiye Fırıncı
author_sort Rukiye Fırıncı
title N-BUTYL SUBSTITUTED N-HETEROCYCLIC CARBENE-PD(II)-PYRIDINE (PEPPSI) COMPLEXES: SYNTHESIS, CHARACTERIZATION AND CATALYTIC ACTIVITY IN THE SUZUKI-MIYAURA REACTION
title_short N-BUTYL SUBSTITUTED N-HETEROCYCLIC CARBENE-PD(II)-PYRIDINE (PEPPSI) COMPLEXES: SYNTHESIS, CHARACTERIZATION AND CATALYTIC ACTIVITY IN THE SUZUKI-MIYAURA REACTION
title_full N-BUTYL SUBSTITUTED N-HETEROCYCLIC CARBENE-PD(II)-PYRIDINE (PEPPSI) COMPLEXES: SYNTHESIS, CHARACTERIZATION AND CATALYTIC ACTIVITY IN THE SUZUKI-MIYAURA REACTION
title_fullStr N-BUTYL SUBSTITUTED N-HETEROCYCLIC CARBENE-PD(II)-PYRIDINE (PEPPSI) COMPLEXES: SYNTHESIS, CHARACTERIZATION AND CATALYTIC ACTIVITY IN THE SUZUKI-MIYAURA REACTION
title_full_unstemmed N-BUTYL SUBSTITUTED N-HETEROCYCLIC CARBENE-PD(II)-PYRIDINE (PEPPSI) COMPLEXES: SYNTHESIS, CHARACTERIZATION AND CATALYTIC ACTIVITY IN THE SUZUKI-MIYAURA REACTION
title_sort n-butyl substituted n-heterocyclic carbene-pd(ii)-pyridine (peppsi) complexes: synthesis, characterization and catalytic activity in the suzuki-miyaura reaction
publisher Turkish Chemical Society
series Journal of the Turkish Chemical Society, Section A: Chemistry
issn 2149-0120
publishDate 2016-08-01
description A series of N-butyl substituted imidazolium salts, (1a-c) and their pyridine enhanced precatalyst preparation stabilization and initiation (PEPPSI) themed palladium N-heterocyclic carbene complexes (2a-c) were synthesized and characterized. Pd-NHC complexes were fully determined by elemental analysis and spectroscopic. The synthesized complexes were tested in Suzuki-Miyaura cross-coupling reaction. These complexes were found to be efficient catalysts for the Suzuki-Miyaura reaction of phenylboronic acid with aryl bromides.
url http://dergipark.gov.tr/jotcsa/issue/27290/287258?publisher=turchemsoc
work_keys_str_mv AT rukiyefırıncı nbutylsubstitutednheterocycliccarbenepdiipyridinepeppsicomplexessynthesischaracterizationandcatalyticactivityinthesuzukimiyaurareaction
_version_ 1725310717877288960

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