Selective on-surface covalent coupling based on metal-organic coordination template

Synthesizing precise conjugated nanostructures on a surface requires fine control over the covalent reaction pathways. Here, the authors show that reversible coordinative bonds can be used to template on-surface C-C coupling reactions, guiding the formation of porous organic nanoribbons.

Bibliographic Details
Main Authors: Shuaipeng Xing, Zhe Zhang, Xiyu Fei, Wei Zhao, Ran Zhang, Tao Lin, Danli Zhao, Huanxin Ju, Hu Xu, Jian Fan, Junfa Zhu, Yu-qiang Ma, Ziliang Shi
Format: Article
Language:English
Published: Nature Publishing Group 2019-01-01
Series:Nature Communications
Online Access:https://doi.org/10.1038/s41467-018-07933-0
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spelling doaj-2e42af9b1bf3465283d473aa6d5146e62021-05-11T12:24:38ZengNature Publishing GroupNature Communications2041-17232019-01-0110111010.1038/s41467-018-07933-0Selective on-surface covalent coupling based on metal-organic coordination templateShuaipeng Xing0Zhe Zhang1Xiyu Fei2Wei Zhao3Ran Zhang4Tao Lin5Danli Zhao6Huanxin Ju7Hu Xu8Jian Fan9Junfa Zhu10Yu-qiang Ma11Ziliang Shi12Center for Soft Condensed Matter Physics and Interdisciplinary Research and School of Physical Science and Technology, Soochow UniversityDepartment of Physics, Southern University of Science and TechnologyInstitute of Functional Nano and Soft Materials (FUNSOM), Soochow UniversityInstitute for Advanced Study, Shenzhen UniversityDepartment of Physics, The Hong Kong University of Science and TechnologyCollege of New Materials and New Energies, Shenzhen Technology UniversityInstitute of Functional Nano and Soft Materials (FUNSOM), Soochow UniversityNational Synchrotron Radiation Laboratory, University of Science and Technology of ChinaDepartment of Physics, Southern University of Science and TechnologyInstitute of Functional Nano and Soft Materials (FUNSOM), Soochow UniversityNational Synchrotron Radiation Laboratory, University of Science and Technology of ChinaCenter for Soft Condensed Matter Physics and Interdisciplinary Research and School of Physical Science and Technology, Soochow UniversityCenter for Soft Condensed Matter Physics and Interdisciplinary Research and School of Physical Science and Technology, Soochow UniversitySynthesizing precise conjugated nanostructures on a surface requires fine control over the covalent reaction pathways. Here, the authors show that reversible coordinative bonds can be used to template on-surface C-C coupling reactions, guiding the formation of porous organic nanoribbons.https://doi.org/10.1038/s41467-018-07933-0
collection DOAJ
language English
format Article
sources DOAJ
author Shuaipeng Xing
Zhe Zhang
Xiyu Fei
Wei Zhao
Ran Zhang
Tao Lin
Danli Zhao
Huanxin Ju
Hu Xu
Jian Fan
Junfa Zhu
Yu-qiang Ma
Ziliang Shi
spellingShingle Shuaipeng Xing
Zhe Zhang
Xiyu Fei
Wei Zhao
Ran Zhang
Tao Lin
Danli Zhao
Huanxin Ju
Hu Xu
Jian Fan
Junfa Zhu
Yu-qiang Ma
Ziliang Shi
Selective on-surface covalent coupling based on metal-organic coordination template
Nature Communications
author_facet Shuaipeng Xing
Zhe Zhang
Xiyu Fei
Wei Zhao
Ran Zhang
Tao Lin
Danli Zhao
Huanxin Ju
Hu Xu
Jian Fan
Junfa Zhu
Yu-qiang Ma
Ziliang Shi
author_sort Shuaipeng Xing
title Selective on-surface covalent coupling based on metal-organic coordination template
title_short Selective on-surface covalent coupling based on metal-organic coordination template
title_full Selective on-surface covalent coupling based on metal-organic coordination template
title_fullStr Selective on-surface covalent coupling based on metal-organic coordination template
title_full_unstemmed Selective on-surface covalent coupling based on metal-organic coordination template
title_sort selective on-surface covalent coupling based on metal-organic coordination template
publisher Nature Publishing Group
series Nature Communications
issn 2041-1723
publishDate 2019-01-01
description Synthesizing precise conjugated nanostructures on a surface requires fine control over the covalent reaction pathways. Here, the authors show that reversible coordinative bonds can be used to template on-surface C-C coupling reactions, guiding the formation of porous organic nanoribbons.
url https://doi.org/10.1038/s41467-018-07933-0
work_keys_str_mv AT shuaipengxing selectiveonsurfacecovalentcouplingbasedonmetalorganiccoordinationtemplate
AT zhezhang selectiveonsurfacecovalentcouplingbasedonmetalorganiccoordinationtemplate
AT xiyufei selectiveonsurfacecovalentcouplingbasedonmetalorganiccoordinationtemplate
AT weizhao selectiveonsurfacecovalentcouplingbasedonmetalorganiccoordinationtemplate
AT ranzhang selectiveonsurfacecovalentcouplingbasedonmetalorganiccoordinationtemplate
AT taolin selectiveonsurfacecovalentcouplingbasedonmetalorganiccoordinationtemplate
AT danlizhao selectiveonsurfacecovalentcouplingbasedonmetalorganiccoordinationtemplate
AT huanxinju selectiveonsurfacecovalentcouplingbasedonmetalorganiccoordinationtemplate
AT huxu selectiveonsurfacecovalentcouplingbasedonmetalorganiccoordinationtemplate
AT jianfan selectiveonsurfacecovalentcouplingbasedonmetalorganiccoordinationtemplate
AT junfazhu selectiveonsurfacecovalentcouplingbasedonmetalorganiccoordinationtemplate
AT yuqiangma selectiveonsurfacecovalentcouplingbasedonmetalorganiccoordinationtemplate
AT ziliangshi selectiveonsurfacecovalentcouplingbasedonmetalorganiccoordinationtemplate
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