Selective on-surface covalent coupling based on metal-organic coordination template
Synthesizing precise conjugated nanostructures on a surface requires fine control over the covalent reaction pathways. Here, the authors show that reversible coordinative bonds can be used to template on-surface C-C coupling reactions, guiding the formation of porous organic nanoribbons.
Main Authors: | , , , , , , , , , , , , |
---|---|
Format: | Article |
Language: | English |
Published: |
Nature Publishing Group
2019-01-01
|
Series: | Nature Communications |
Online Access: | https://doi.org/10.1038/s41467-018-07933-0 |
id |
doaj-2e42af9b1bf3465283d473aa6d5146e6 |
---|---|
record_format |
Article |
spelling |
doaj-2e42af9b1bf3465283d473aa6d5146e62021-05-11T12:24:38ZengNature Publishing GroupNature Communications2041-17232019-01-0110111010.1038/s41467-018-07933-0Selective on-surface covalent coupling based on metal-organic coordination templateShuaipeng Xing0Zhe Zhang1Xiyu Fei2Wei Zhao3Ran Zhang4Tao Lin5Danli Zhao6Huanxin Ju7Hu Xu8Jian Fan9Junfa Zhu10Yu-qiang Ma11Ziliang Shi12Center for Soft Condensed Matter Physics and Interdisciplinary Research and School of Physical Science and Technology, Soochow UniversityDepartment of Physics, Southern University of Science and TechnologyInstitute of Functional Nano and Soft Materials (FUNSOM), Soochow UniversityInstitute for Advanced Study, Shenzhen UniversityDepartment of Physics, The Hong Kong University of Science and TechnologyCollege of New Materials and New Energies, Shenzhen Technology UniversityInstitute of Functional Nano and Soft Materials (FUNSOM), Soochow UniversityNational Synchrotron Radiation Laboratory, University of Science and Technology of ChinaDepartment of Physics, Southern University of Science and TechnologyInstitute of Functional Nano and Soft Materials (FUNSOM), Soochow UniversityNational Synchrotron Radiation Laboratory, University of Science and Technology of ChinaCenter for Soft Condensed Matter Physics and Interdisciplinary Research and School of Physical Science and Technology, Soochow UniversityCenter for Soft Condensed Matter Physics and Interdisciplinary Research and School of Physical Science and Technology, Soochow UniversitySynthesizing precise conjugated nanostructures on a surface requires fine control over the covalent reaction pathways. Here, the authors show that reversible coordinative bonds can be used to template on-surface C-C coupling reactions, guiding the formation of porous organic nanoribbons.https://doi.org/10.1038/s41467-018-07933-0 |
collection |
DOAJ |
language |
English |
format |
Article |
sources |
DOAJ |
author |
Shuaipeng Xing Zhe Zhang Xiyu Fei Wei Zhao Ran Zhang Tao Lin Danli Zhao Huanxin Ju Hu Xu Jian Fan Junfa Zhu Yu-qiang Ma Ziliang Shi |
spellingShingle |
Shuaipeng Xing Zhe Zhang Xiyu Fei Wei Zhao Ran Zhang Tao Lin Danli Zhao Huanxin Ju Hu Xu Jian Fan Junfa Zhu Yu-qiang Ma Ziliang Shi Selective on-surface covalent coupling based on metal-organic coordination template Nature Communications |
author_facet |
Shuaipeng Xing Zhe Zhang Xiyu Fei Wei Zhao Ran Zhang Tao Lin Danli Zhao Huanxin Ju Hu Xu Jian Fan Junfa Zhu Yu-qiang Ma Ziliang Shi |
author_sort |
Shuaipeng Xing |
title |
Selective on-surface covalent coupling based on metal-organic coordination template |
title_short |
Selective on-surface covalent coupling based on metal-organic coordination template |
title_full |
Selective on-surface covalent coupling based on metal-organic coordination template |
title_fullStr |
Selective on-surface covalent coupling based on metal-organic coordination template |
title_full_unstemmed |
Selective on-surface covalent coupling based on metal-organic coordination template |
title_sort |
selective on-surface covalent coupling based on metal-organic coordination template |
publisher |
Nature Publishing Group |
series |
Nature Communications |
issn |
2041-1723 |
publishDate |
2019-01-01 |
description |
Synthesizing precise conjugated nanostructures on a surface requires fine control over the covalent reaction pathways. Here, the authors show that reversible coordinative bonds can be used to template on-surface C-C coupling reactions, guiding the formation of porous organic nanoribbons. |
url |
https://doi.org/10.1038/s41467-018-07933-0 |
work_keys_str_mv |
AT shuaipengxing selectiveonsurfacecovalentcouplingbasedonmetalorganiccoordinationtemplate AT zhezhang selectiveonsurfacecovalentcouplingbasedonmetalorganiccoordinationtemplate AT xiyufei selectiveonsurfacecovalentcouplingbasedonmetalorganiccoordinationtemplate AT weizhao selectiveonsurfacecovalentcouplingbasedonmetalorganiccoordinationtemplate AT ranzhang selectiveonsurfacecovalentcouplingbasedonmetalorganiccoordinationtemplate AT taolin selectiveonsurfacecovalentcouplingbasedonmetalorganiccoordinationtemplate AT danlizhao selectiveonsurfacecovalentcouplingbasedonmetalorganiccoordinationtemplate AT huanxinju selectiveonsurfacecovalentcouplingbasedonmetalorganiccoordinationtemplate AT huxu selectiveonsurfacecovalentcouplingbasedonmetalorganiccoordinationtemplate AT jianfan selectiveonsurfacecovalentcouplingbasedonmetalorganiccoordinationtemplate AT junfazhu selectiveonsurfacecovalentcouplingbasedonmetalorganiccoordinationtemplate AT yuqiangma selectiveonsurfacecovalentcouplingbasedonmetalorganiccoordinationtemplate AT ziliangshi selectiveonsurfacecovalentcouplingbasedonmetalorganiccoordinationtemplate |
_version_ |
1721444790953836544 |