6,6′-Dimethoxy-2,2′-[(E,E′)-(4-chloro-m-phenylene)bis(nitrilomethylidyne)]diphenol

6,6′-Dimethoxy-2,2′-[(E,E′)-(4-chloro-m-phenylene)bis(nitrilomethylidyne)]diphenol

The title compound, C22H19ClN2O4, has the appearance of a warped butterfly. One 2-hydroxy-3-methoxybenzylideneamino fragment is planar [with a maximum deviation of 0.056 (3) Å] and forms a dihedral angle of 9.85 (9)° with the centra...

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Main Authors: Bohari M. Yamin, Siti Najihah A. Bakar, Karimah Kassim, Hadariah Bahron
Format: Article
Language:English
Published: International Union of Crystallography 2009-10-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536809037386
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spelling doaj-2e27a9ad161646c6ab4b32e418c173eb2020-11-25T00:20:49ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682009-10-016510o2573o257310.1107/S16005368090373866,6′-Dimethoxy-2,2′-[(E,E′)-(4-chloro-m-phenylene)bis(nitrilomethylidyne)]diphenolBohari M. YaminSiti Najihah A. BakarKarimah KassimHadariah BahronThe title compound, C22H19ClN2O4, has the appearance of a warped butterfly. One 2-hydroxy-3-methoxybenzylideneamino fragment is planar [with a maximum deviation of 0.056 (3) Å] and forms a dihedral angle of 9.85 (9)° with the central benzene ring. The other fragment is not planar; however, the methoxyphenol group is planar [with the maximum deviation of 0.033 (2) Å] and makes a dihedral angle of 41.7 (3)° with the central benzene ring. The molecule is stabilized by intramolecular O—H...N hydrogen bonding. The crystal structure is stabilized by weak intermolecular C—H...O hydrogen bonding and C—H...π interactions. http://scripts.iucr.org/cgi-bin/paper?S1600536809037386
collection DOAJ
language English
format Article
sources DOAJ
author Bohari M. Yamin
Siti Najihah A. Bakar
Karimah Kassim
Hadariah Bahron
spellingShingle Bohari M. Yamin
Siti Najihah A. Bakar
Karimah Kassim
Hadariah Bahron
6,6′-Dimethoxy-2,2′-[(E,E′)-(4-chloro-m-phenylene)bis(nitrilomethylidyne)]diphenol
Acta Crystallographica Section E
author_facet Bohari M. Yamin
Siti Najihah A. Bakar
Karimah Kassim
Hadariah Bahron
author_sort Bohari M. Yamin
title 6,6′-Dimethoxy-2,2′-[(E,E′)-(4-chloro-m-phenylene)bis(nitrilomethylidyne)]diphenol
title_short 6,6′-Dimethoxy-2,2′-[(E,E′)-(4-chloro-m-phenylene)bis(nitrilomethylidyne)]diphenol
title_full 6,6′-Dimethoxy-2,2′-[(E,E′)-(4-chloro-m-phenylene)bis(nitrilomethylidyne)]diphenol
title_fullStr 6,6′-Dimethoxy-2,2′-[(E,E′)-(4-chloro-m-phenylene)bis(nitrilomethylidyne)]diphenol
title_full_unstemmed 6,6′-Dimethoxy-2,2′-[(E,E′)-(4-chloro-m-phenylene)bis(nitrilomethylidyne)]diphenol
title_sort 6,6′-dimethoxy-2,2′-[(e,e′)-(4-chloro-m-phenylene)bis(nitrilomethylidyne)]diphenol
publisher International Union of Crystallography
series Acta Crystallographica Section E
issn 1600-5368
publishDate 2009-10-01
description The title compound, C22H19ClN2O4, has the appearance of a warped butterfly. One 2-hydroxy-3-methoxybenzylideneamino fragment is planar [with a maximum deviation of 0.056 (3) Å] and forms a dihedral angle of 9.85 (9)° with the central benzene ring. The other fragment is not planar; however, the methoxyphenol group is planar [with the maximum deviation of 0.033 (2) Å] and makes a dihedral angle of 41.7 (3)° with the central benzene ring. The molecule is stabilized by intramolecular O—H...N hydrogen bonding. The crystal structure is stabilized by weak intermolecular C—H...O hydrogen bonding and C—H...π interactions.
url http://scripts.iucr.org/cgi-bin/paper?S1600536809037386
work_keys_str_mv AT boharimyamin 66amp8242dimethoxy22amp8242eeamp82424chloromphenylenebisnitrilomethylidynediphenol
AT sitinajihahabakar 66amp8242dimethoxy22amp8242eeamp82424chloromphenylenebisnitrilomethylidynediphenol
AT karimahkassim 66amp8242dimethoxy22amp8242eeamp82424chloromphenylenebisnitrilomethylidynediphenol
AT hadariahbahron 66amp8242dimethoxy22amp8242eeamp82424chloromphenylenebisnitrilomethylidynediphenol
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