6,6′-Dimethoxy-2,2′-[(E,E′)-(4-chloro-m-phenylene)bis(nitrilomethylidyne)]diphenol
The title compound, C22H19ClN2O4, has the appearance of a warped butterfly. One 2-hydroxy-3-methoxybenzylideneamino fragment is planar [with a maximum deviation of 0.056 (3) Å] and forms a dihedral angle of 9.85 (9)° with the centra...
| Main Authors: | , , , |
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| Format: | Article |
| Language: | English |
| Published: |
International Union of Crystallography
2009-10-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536809037386 |
| Summary: | The title compound, C22H19ClN2O4, has the appearance of a warped butterfly. One 2-hydroxy-3-methoxybenzylideneamino fragment is planar [with a maximum deviation of 0.056 (3) Å] and forms a dihedral angle of 9.85 (9)° with the central benzene ring. The other fragment is not planar; however, the methoxyphenol group is planar [with the maximum deviation of 0.033 (2) Å] and makes a dihedral angle of 41.7 (3)° with the central benzene ring. The molecule is stabilized by intramolecular O—H...N hydrogen bonding. The crystal structure is stabilized by weak intermolecular C—H...O hydrogen bonding and C—H...π interactions. |
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| ISSN: | 1600-5368 |