Poly[bis(μ2-5-{4-[(1H-imidazol-1-yl)methyl]phenyl}tetrazolato)zinc]

In the title compound, [Zn(C11H9N6)2]n, the ZnII atom lies on an inversion center and is coordinated by four N atoms from four 5-[4-(1H-imidazol-1-ylmethyl)phenyl]tetrazolate ligands in a distorted tetrahedral geometry. The ligands bridge the ZnII atoms, leading to the formation of a two-dimensional...

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Main Author: Zhe Song
Format: Article
Language:English
Published: International Union of Crystallography 2013-02-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536812050672
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spelling doaj-2e0ad777e8b54540a90c1766423481262020-11-24T21:26:38ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682013-02-01692m85m8510.1107/S1600536812050672Poly[bis(μ2-5-{4-[(1H-imidazol-1-yl)methyl]phenyl}tetrazolato)zinc]Zhe SongIn the title compound, [Zn(C11H9N6)2]n, the ZnII atom lies on an inversion center and is coordinated by four N atoms from four 5-[4-(1H-imidazol-1-ylmethyl)phenyl]tetrazolate ligands in a distorted tetrahedral geometry. The ligands bridge the ZnII atoms, leading to the formation of a two-dimensional network parallel to (010). The structure is further stabilized by C—H...N, C—H...π and π–π [centroid–centroid distance = 3.7523 (11) Å] interactions within the network.http://scripts.iucr.org/cgi-bin/paper?S1600536812050672
collection DOAJ
language English
format Article
sources DOAJ
author Zhe Song
spellingShingle Zhe Song
Poly[bis(μ2-5-{4-[(1H-imidazol-1-yl)methyl]phenyl}tetrazolato)zinc]
Acta Crystallographica Section E
author_facet Zhe Song
author_sort Zhe Song
title Poly[bis(μ2-5-{4-[(1H-imidazol-1-yl)methyl]phenyl}tetrazolato)zinc]
title_short Poly[bis(μ2-5-{4-[(1H-imidazol-1-yl)methyl]phenyl}tetrazolato)zinc]
title_full Poly[bis(μ2-5-{4-[(1H-imidazol-1-yl)methyl]phenyl}tetrazolato)zinc]
title_fullStr Poly[bis(μ2-5-{4-[(1H-imidazol-1-yl)methyl]phenyl}tetrazolato)zinc]
title_full_unstemmed Poly[bis(μ2-5-{4-[(1H-imidazol-1-yl)methyl]phenyl}tetrazolato)zinc]
title_sort poly[bis(μ2-5-{4-[(1h-imidazol-1-yl)methyl]phenyl}tetrazolato)zinc]
publisher International Union of Crystallography
series Acta Crystallographica Section E
issn 1600-5368
publishDate 2013-02-01
description In the title compound, [Zn(C11H9N6)2]n, the ZnII atom lies on an inversion center and is coordinated by four N atoms from four 5-[4-(1H-imidazol-1-ylmethyl)phenyl]tetrazolate ligands in a distorted tetrahedral geometry. The ligands bridge the ZnII atoms, leading to the formation of a two-dimensional network parallel to (010). The structure is further stabilized by C—H...N, C—H...π and π–π [centroid–centroid distance = 3.7523 (11) Å] interactions within the network.
url http://scripts.iucr.org/cgi-bin/paper?S1600536812050672
work_keys_str_mv AT zhesong polybis9562541himidazol1ylmethylphenyltetrazolatozinc
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