2-(2,4-Difluorophenyl)-4,5-dimethyl-1-(4-methylphenyl)-1H-imidazole monohydrate

2-(2,4-Difluorophenyl)-4,5-dimethyl-1-(4-methylphenyl)-1H-imidazole monohydrate

The asymmetric unit of the title compound, C18H16F2N2·H2O, contains two independent molecules (A and B), and two independent water molecules of crystallization. In molecule A, the imidazole ring makes dihedral angles of 47.46 (7) and 60.98 (6)° with the 2,4-difl...

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Main Authors: Natesan Srinivasan, Syed Rafee Ahamed Rizwana Begum, Ramu Hema, Balasubramanian Sridhar, Azhagan Ganapathi Anitha
Format: Article
Language:English
Published: International Union of Crystallography 2013-11-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536813026354
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spelling doaj-2df3b9619785471c8fc14d94e2a508a72020-11-25T01:33:28ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682013-11-016911o1599o160010.1107/S16005368130263542-(2,4-Difluorophenyl)-4,5-dimethyl-1-(4-methylphenyl)-1H-imidazole monohydrateNatesan SrinivasanSyed Rafee Ahamed Rizwana BegumRamu HemaBalasubramanian SridharAzhagan Ganapathi AnithaThe asymmetric unit of the title compound, C18H16F2N2·H2O, contains two independent molecules (A and B), and two independent water molecules of crystallization. In molecule A, the imidazole ring makes dihedral angles of 47.46 (7) and 60.98 (6)° with the 2,4-difluorophenyl and methylphenyl rings, respectively. The corresponding angles in molecule B are 45.85 (7) and 62.78 (7)°, respectively. The dihedral angle between the two benzene rings is 64.98 (7)° in molecule A and 65.53 (7)° in molecule B. In the crystal, the two independent molecules are linked by O—H...N and O—H...O hydrogen bonds, forming chains propagating along [100]. These chains are linked via C—H...F hydrogen bonds, forming slab-like two-dimensional networks lying parallel to (001).http://scripts.iucr.org/cgi-bin/paper?S1600536813026354
collection DOAJ
language English
format Article
sources DOAJ
author Natesan Srinivasan
Syed Rafee Ahamed Rizwana Begum
Ramu Hema
Balasubramanian Sridhar
Azhagan Ganapathi Anitha
spellingShingle Natesan Srinivasan
Syed Rafee Ahamed Rizwana Begum
Ramu Hema
Balasubramanian Sridhar
Azhagan Ganapathi Anitha
2-(2,4-Difluorophenyl)-4,5-dimethyl-1-(4-methylphenyl)-1H-imidazole monohydrate
Acta Crystallographica Section E
author_facet Natesan Srinivasan
Syed Rafee Ahamed Rizwana Begum
Ramu Hema
Balasubramanian Sridhar
Azhagan Ganapathi Anitha
author_sort Natesan Srinivasan
title 2-(2,4-Difluorophenyl)-4,5-dimethyl-1-(4-methylphenyl)-1H-imidazole monohydrate
title_short 2-(2,4-Difluorophenyl)-4,5-dimethyl-1-(4-methylphenyl)-1H-imidazole monohydrate
title_full 2-(2,4-Difluorophenyl)-4,5-dimethyl-1-(4-methylphenyl)-1H-imidazole monohydrate
title_fullStr 2-(2,4-Difluorophenyl)-4,5-dimethyl-1-(4-methylphenyl)-1H-imidazole monohydrate
title_full_unstemmed 2-(2,4-Difluorophenyl)-4,5-dimethyl-1-(4-methylphenyl)-1H-imidazole monohydrate
title_sort 2-(2,4-difluorophenyl)-4,5-dimethyl-1-(4-methylphenyl)-1h-imidazole monohydrate
publisher International Union of Crystallography
series Acta Crystallographica Section E
issn 1600-5368
publishDate 2013-11-01
description The asymmetric unit of the title compound, C18H16F2N2·H2O, contains two independent molecules (A and B), and two independent water molecules of crystallization. In molecule A, the imidazole ring makes dihedral angles of 47.46 (7) and 60.98 (6)° with the 2,4-difluorophenyl and methylphenyl rings, respectively. The corresponding angles in molecule B are 45.85 (7) and 62.78 (7)°, respectively. The dihedral angle between the two benzene rings is 64.98 (7)° in molecule A and 65.53 (7)° in molecule B. In the crystal, the two independent molecules are linked by O—H...N and O—H...O hydrogen bonds, forming chains propagating along [100]. These chains are linked via C—H...F hydrogen bonds, forming slab-like two-dimensional networks lying parallel to (001).
url http://scripts.iucr.org/cgi-bin/paper?S1600536813026354
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AT syedrafeeahamedrizwanabegum 224difluorophenyl45dimethyl14methylphenyl1himidazolemonohydrate
AT ramuhema 224difluorophenyl45dimethyl14methylphenyl1himidazolemonohydrate
AT balasubramaniansridhar 224difluorophenyl45dimethyl14methylphenyl1himidazolemonohydrate
AT azhaganganapathianitha 224difluorophenyl45dimethyl14methylphenyl1himidazolemonohydrate
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