Sb2Se3 assembling Sb2O3@ attapulgite as an emerging composites for catalytic hydrogenation of p-nitrophenol
Abstract The construction and application of a new type of composite material are achieved more and more attention. However, expected Sb2Se3/attapulgite composites aim to use the low price, and high adsorption of attapulgite in assembling Sb2Se3 is quite difficult to be acquired by a facile and beni...
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doaj-2de4d02aa64245c48933e50fbb4bb3512020-12-08T00:36:35ZengNature Publishing GroupScientific Reports2045-23222017-06-017111110.1038/s41598-017-03281-zSb2Se3 assembling Sb2O3@ attapulgite as an emerging composites for catalytic hydrogenation of p-nitrophenolLin Tan0Aidong Tang1Yue Zou2Mei Long3Yi Zhang4Jin Ouyang5Jing Chen6School of Chemistry and Chemical Engineering, Central South UniversitySchool of Chemistry and Chemical Engineering, Central South UniversitySchool of Chemistry and Chemical Engineering, Central South UniversitySchool of Chemistry and Chemical Engineering, Central South UniversityCentre for Mineral Materials, School of Minerals Processing and Bioengineering, Central South UniversityCentre for Mineral Materials, School of Minerals Processing and Bioengineering, Central South UniversityKey Laboratory of Palygorskite Science and Applied Technology of Jiangsu Province, Huaiyin Institute of TechnologyAbstract The construction and application of a new type of composite material are achieved more and more attention. However, expected Sb2Se3/attapulgite composites aim to use the low price, and high adsorption of attapulgite in assembling Sb2Se3 is quite difficult to be acquired by a facile and benign environmental hydrothermal method. In this manuscript, we developed a new way for preparation of an emerging composite by means of Sb2O3 as a media linking Sb2Se3 and attapulgite together, and finally won an emerging composite Sb2Se3/Sb2O3@attapulgite, which presented an excellent catalytic properties for catalytic hydrogenation of p-nitrophenol. It was noted that the Sb2Se3/Sb2O3@attapulgite composites exhibited a high conversion rate for the hydrogenation of p-nitrophenol that was up to 90.7% within 15 min, which was far more than the 61.5% of Sb2Se3 sample. The excellent catalytic performance was attributed to the highly dispersion Sb2Se3 microbelts and Sb2Se3@Sb2O3@attapulgite rods, which would improve the adsorption of the reactant species and facility electronic transfer process of the catalytic hydrogenation of p-nitrophenol.https://doi.org/10.1038/s41598-017-03281-z |
collection |
DOAJ |
language |
English |
format |
Article |
sources |
DOAJ |
author |
Lin Tan Aidong Tang Yue Zou Mei Long Yi Zhang Jin Ouyang Jing Chen |
spellingShingle |
Lin Tan Aidong Tang Yue Zou Mei Long Yi Zhang Jin Ouyang Jing Chen Sb2Se3 assembling Sb2O3@ attapulgite as an emerging composites for catalytic hydrogenation of p-nitrophenol Scientific Reports |
author_facet |
Lin Tan Aidong Tang Yue Zou Mei Long Yi Zhang Jin Ouyang Jing Chen |
author_sort |
Lin Tan |
title |
Sb2Se3 assembling Sb2O3@ attapulgite as an emerging composites for catalytic hydrogenation of p-nitrophenol |
title_short |
Sb2Se3 assembling Sb2O3@ attapulgite as an emerging composites for catalytic hydrogenation of p-nitrophenol |
title_full |
Sb2Se3 assembling Sb2O3@ attapulgite as an emerging composites for catalytic hydrogenation of p-nitrophenol |
title_fullStr |
Sb2Se3 assembling Sb2O3@ attapulgite as an emerging composites for catalytic hydrogenation of p-nitrophenol |
title_full_unstemmed |
Sb2Se3 assembling Sb2O3@ attapulgite as an emerging composites for catalytic hydrogenation of p-nitrophenol |
title_sort |
sb2se3 assembling sb2o3@ attapulgite as an emerging composites for catalytic hydrogenation of p-nitrophenol |
publisher |
Nature Publishing Group |
series |
Scientific Reports |
issn |
2045-2322 |
publishDate |
2017-06-01 |
description |
Abstract The construction and application of a new type of composite material are achieved more and more attention. However, expected Sb2Se3/attapulgite composites aim to use the low price, and high adsorption of attapulgite in assembling Sb2Se3 is quite difficult to be acquired by a facile and benign environmental hydrothermal method. In this manuscript, we developed a new way for preparation of an emerging composite by means of Sb2O3 as a media linking Sb2Se3 and attapulgite together, and finally won an emerging composite Sb2Se3/Sb2O3@attapulgite, which presented an excellent catalytic properties for catalytic hydrogenation of p-nitrophenol. It was noted that the Sb2Se3/Sb2O3@attapulgite composites exhibited a high conversion rate for the hydrogenation of p-nitrophenol that was up to 90.7% within 15 min, which was far more than the 61.5% of Sb2Se3 sample. The excellent catalytic performance was attributed to the highly dispersion Sb2Se3 microbelts and Sb2Se3@Sb2O3@attapulgite rods, which would improve the adsorption of the reactant species and facility electronic transfer process of the catalytic hydrogenation of p-nitrophenol. |
url |
https://doi.org/10.1038/s41598-017-03281-z |
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