Sb2Se3 assembling Sb2O3@ attapulgite as an emerging composites for catalytic hydrogenation of p-nitrophenol

Abstract The construction and application of a new type of composite material are achieved more and more attention. However, expected Sb2Se3/attapulgite composites aim to use the low price, and high adsorption of attapulgite in assembling Sb2Se3 is quite difficult to be acquired by a facile and beni...

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Main Authors: Lin Tan, Aidong Tang, Yue Zou, Mei Long, Yi Zhang, Jin Ouyang, Jing Chen
Format: Article
Language:English
Published: Nature Publishing Group 2017-06-01
Series:Scientific Reports
Online Access:https://doi.org/10.1038/s41598-017-03281-z
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spelling doaj-2de4d02aa64245c48933e50fbb4bb3512020-12-08T00:36:35ZengNature Publishing GroupScientific Reports2045-23222017-06-017111110.1038/s41598-017-03281-zSb2Se3 assembling Sb2O3@ attapulgite as an emerging composites for catalytic hydrogenation of p-nitrophenolLin Tan0Aidong Tang1Yue Zou2Mei Long3Yi Zhang4Jin Ouyang5Jing Chen6School of Chemistry and Chemical Engineering, Central South UniversitySchool of Chemistry and Chemical Engineering, Central South UniversitySchool of Chemistry and Chemical Engineering, Central South UniversitySchool of Chemistry and Chemical Engineering, Central South UniversityCentre for Mineral Materials, School of Minerals Processing and Bioengineering, Central South UniversityCentre for Mineral Materials, School of Minerals Processing and Bioengineering, Central South UniversityKey Laboratory of Palygorskite Science and Applied Technology of Jiangsu Province, Huaiyin Institute of TechnologyAbstract The construction and application of a new type of composite material are achieved more and more attention. However, expected Sb2Se3/attapulgite composites aim to use the low price, and high adsorption of attapulgite in assembling Sb2Se3 is quite difficult to be acquired by a facile and benign environmental hydrothermal method. In this manuscript, we developed a new way for preparation of an emerging composite by means of Sb2O3 as a media linking Sb2Se3 and attapulgite together, and finally won an emerging composite Sb2Se3/Sb2O3@attapulgite, which presented an excellent catalytic properties for catalytic hydrogenation of p-nitrophenol. It was noted that the Sb2Se3/Sb2O3@attapulgite composites exhibited a high conversion rate for the hydrogenation of p-nitrophenol that was up to 90.7% within 15 min, which was far more than the 61.5% of Sb2Se3 sample. The excellent catalytic performance was attributed to the highly dispersion Sb2Se3 microbelts and Sb2Se3@Sb2O3@attapulgite rods, which would improve the adsorption of the reactant species and facility electronic transfer process of the catalytic hydrogenation of p-nitrophenol.https://doi.org/10.1038/s41598-017-03281-z
collection DOAJ
language English
format Article
sources DOAJ
author Lin Tan
Aidong Tang
Yue Zou
Mei Long
Yi Zhang
Jin Ouyang
Jing Chen
spellingShingle Lin Tan
Aidong Tang
Yue Zou
Mei Long
Yi Zhang
Jin Ouyang
Jing Chen
Sb2Se3 assembling Sb2O3@ attapulgite as an emerging composites for catalytic hydrogenation of p-nitrophenol
Scientific Reports
author_facet Lin Tan
Aidong Tang
Yue Zou
Mei Long
Yi Zhang
Jin Ouyang
Jing Chen
author_sort Lin Tan
title Sb2Se3 assembling Sb2O3@ attapulgite as an emerging composites for catalytic hydrogenation of p-nitrophenol
title_short Sb2Se3 assembling Sb2O3@ attapulgite as an emerging composites for catalytic hydrogenation of p-nitrophenol
title_full Sb2Se3 assembling Sb2O3@ attapulgite as an emerging composites for catalytic hydrogenation of p-nitrophenol
title_fullStr Sb2Se3 assembling Sb2O3@ attapulgite as an emerging composites for catalytic hydrogenation of p-nitrophenol
title_full_unstemmed Sb2Se3 assembling Sb2O3@ attapulgite as an emerging composites for catalytic hydrogenation of p-nitrophenol
title_sort sb2se3 assembling sb2o3@ attapulgite as an emerging composites for catalytic hydrogenation of p-nitrophenol
publisher Nature Publishing Group
series Scientific Reports
issn 2045-2322
publishDate 2017-06-01
description Abstract The construction and application of a new type of composite material are achieved more and more attention. However, expected Sb2Se3/attapulgite composites aim to use the low price, and high adsorption of attapulgite in assembling Sb2Se3 is quite difficult to be acquired by a facile and benign environmental hydrothermal method. In this manuscript, we developed a new way for preparation of an emerging composite by means of Sb2O3 as a media linking Sb2Se3 and attapulgite together, and finally won an emerging composite Sb2Se3/Sb2O3@attapulgite, which presented an excellent catalytic properties for catalytic hydrogenation of p-nitrophenol. It was noted that the Sb2Se3/Sb2O3@attapulgite composites exhibited a high conversion rate for the hydrogenation of p-nitrophenol that was up to 90.7% within 15 min, which was far more than the 61.5% of Sb2Se3 sample. The excellent catalytic performance was attributed to the highly dispersion Sb2Se3 microbelts and Sb2Se3@Sb2O3@attapulgite rods, which would improve the adsorption of the reactant species and facility electronic transfer process of the catalytic hydrogenation of p-nitrophenol.
url https://doi.org/10.1038/s41598-017-03281-z
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