Bis(3,5-dimethoxy-2-{[2-(pyridin-2-yl)ethylimino-κN]methyl}phenolato-κO)bis(dimethyl sulfoxide)manganese(III) perchlorate methanol 0.774-solvate

Bis(3,5-dimethoxy-2-{[2-(pyridin-2-yl)ethylimino-κN]methyl}phenolato-κO)bis(dimethyl sulfoxide)manganese(III) perchlorate methanol 0.774-solvate

The title compound, [Mn(C16H17N2O3)2(C2H6OS)2]ClO4·0.774CH3OH, comprises a central octahedrally coordinated MnIII cation, with two bidentate Schiff base ligands occupying the equatorial positions and two dimethyl sulfoxide (DMSO) ligands occupying the axial positions. There are two independant catio...

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Bibliographic Details
Main Authors: Rita Egekenze, Yilma Gultneh, Ray J. Butcher
Format: Article
Language:English
Published: International Union of Crystallography 2017-10-01
Series:Acta Crystallographica Section E: Crystallographic Communications
Subjects:
crystal structure
MnIII Schiff base complex
Jahn–Teller distortion
DMSO coordination
Online Access:http://scripts.iucr.org/cgi-bin/paper?S205698901701204X

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