Bis[N,N-dimethyl-1-(10H-pyrido[3,2-b][1,4]benzothiazin-10-yl)propan-2-aminium] tetrakis(thiocyanato-κN)cobaltate(II)
The asymmetric unit of the title salt, (C16H20N3S)2[Co(NCS)4], comprises one monovalent isothiopendylium cation and one-half of a divalent thiocyanatocobaltate(II) anion (2 symmetry). The central thiazine ring of the cation is slightly twisted in a boat-like fashion, with r.m.s. deviations from the...
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International Union of Crystallography
2010-07-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536810021367 |
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doaj-2d5491e2e5884c3abf45db7c2fc680fa2020-11-24T21:31:47ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682010-07-01667m772m77310.1107/S1600536810021367Bis[N,N-dimethyl-1-(10H-pyrido[3,2-b][1,4]benzothiazin-10-yl)propan-2-aminium] tetrakis(thiocyanato-κN)cobaltate(II)H. K. ArunkashiS. JeyaseelanSuresh Babu VepuriH. D. RevanasiddappaH. C. DevarajegowdaThe asymmetric unit of the title salt, (C16H20N3S)2[Co(NCS)4], comprises one monovalent isothiopendylium cation and one-half of a divalent thiocyanatocobaltate(II) anion (2 symmetry). The central thiazine ring of the cation is slightly twisted in a boat-like fashion, with r.m.s. deviations from the mean plane of 0.272 (1) and 0.2852 (8) Å for the N and S atoms. The molecular structure of the cation is stabilized by an intramolecular N—H...N hydrogen bond. Within the complex anion, the CoII atom is tetrahedrally surrounded by four N atoms of the thiocyanate ligands. π–π stacking, with a distance of 3.7615 (10) Å between the centroids of benzene and pyridine rings, helps to consolidate the packing. http://scripts.iucr.org/cgi-bin/paper?S1600536810021367 |
| collection |
DOAJ |
| language |
English |
| format |
Article |
| sources |
DOAJ |
| author |
H. K. Arunkashi S. Jeyaseelan Suresh Babu Vepuri H. D. Revanasiddappa H. C. Devarajegowda |
| spellingShingle |
H. K. Arunkashi S. Jeyaseelan Suresh Babu Vepuri H. D. Revanasiddappa H. C. Devarajegowda Bis[N,N-dimethyl-1-(10H-pyrido[3,2-b][1,4]benzothiazin-10-yl)propan-2-aminium] tetrakis(thiocyanato-κN)cobaltate(II) Acta Crystallographica Section E |
| author_facet |
H. K. Arunkashi S. Jeyaseelan Suresh Babu Vepuri H. D. Revanasiddappa H. C. Devarajegowda |
| author_sort |
H. K. Arunkashi |
| title |
Bis[N,N-dimethyl-1-(10H-pyrido[3,2-b][1,4]benzothiazin-10-yl)propan-2-aminium] tetrakis(thiocyanato-κN)cobaltate(II) |
| title_short |
Bis[N,N-dimethyl-1-(10H-pyrido[3,2-b][1,4]benzothiazin-10-yl)propan-2-aminium] tetrakis(thiocyanato-κN)cobaltate(II) |
| title_full |
Bis[N,N-dimethyl-1-(10H-pyrido[3,2-b][1,4]benzothiazin-10-yl)propan-2-aminium] tetrakis(thiocyanato-κN)cobaltate(II) |
| title_fullStr |
Bis[N,N-dimethyl-1-(10H-pyrido[3,2-b][1,4]benzothiazin-10-yl)propan-2-aminium] tetrakis(thiocyanato-κN)cobaltate(II) |
| title_full_unstemmed |
Bis[N,N-dimethyl-1-(10H-pyrido[3,2-b][1,4]benzothiazin-10-yl)propan-2-aminium] tetrakis(thiocyanato-κN)cobaltate(II) |
| title_sort |
bis[n,n-dimethyl-1-(10h-pyrido[3,2-b][1,4]benzothiazin-10-yl)propan-2-aminium] tetrakis(thiocyanato-κn)cobaltate(ii) |
| publisher |
International Union of Crystallography |
| series |
Acta Crystallographica Section E |
| issn |
1600-5368 |
| publishDate |
2010-07-01 |
| description |
The asymmetric unit of the title salt, (C16H20N3S)2[Co(NCS)4], comprises one monovalent isothiopendylium cation and one-half of a divalent thiocyanatocobaltate(II) anion (2 symmetry). The central thiazine ring of the cation is slightly twisted in a boat-like fashion, with r.m.s. deviations from the mean plane of 0.272 (1) and 0.2852 (8) Å for the N and S atoms. The molecular structure of the cation is stabilized by an intramolecular N—H...N hydrogen bond. Within the complex anion, the CoII atom is tetrahedrally surrounded by four N atoms of the thiocyanate ligands. π–π stacking, with a distance of 3.7615 (10) Å between the centroids of benzene and pyridine rings, helps to consolidate the packing. |
| url |
http://scripts.iucr.org/cgi-bin/paper?S1600536810021367 |
| work_keys_str_mv |
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1725959683771990016 |