Chlorido(&#951;4-1,5-cyclooctadiene)[(pentafluoroethyl)diphenylphosphane]iridium(I)

Chlorido(&#951;4-1,5-cyclooctadiene)[(pentafluoroethyl)diphenylphosphane]iridium(I)

The title structure,[IrCl(C8H12)(C14H10F5P)], reveals that (C2F5)PPh2 (pentafluoroethyldiphenylphosphane or pfepp) disrupts the iridium dimer [(cod)IrCl]2 (cod = cycloocta-1,5-diene) by rupturing the bridging chloride ligands and binding in the open coordination site to form (cod)Ir(pfepp)Cl with th...

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Bibliographic Details
Main Authors:	Russell G. Baughman, R. Gregory Peters, Michelle M. Choate
Format:	Article
Language:	English
Published:	International Union of Crystallography 2011-01-01
Series:	Acta Crystallographica Section E
Online Access:	http://scripts.iucr.org/cgi-bin/paper?S160053681005141X

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