tert-Butyl N-{4-methyl-3-[4-(3-pyridyl)pyrimidin-2-yloxy]phenyl}carbamate

tert-Butyl N-{4-methyl-3-[4-(3-pyridyl)pyrimidin-2-yloxy]phenyl}carbamate

In the molecule of the title compound, C21H22N4O3, the pyrimidine ring is oriented at dihedral angles of 0.51 (3) and 50.76 (3)° to the pyridine and benzene rings, respectively. In the crystal structure, intermolecular N—H...N hydrogen bonds lin...

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Main Authors: Shi-Gui Tang, Jian-Qiang Wang, Cheng Guo
Format: Article
Language:English
Published: International Union of Crystallography 2009-08-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536809025604
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spelling doaj-2d3cbcf123f14e3e817013bf1a6e734d2020-11-25T03:27:03ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682009-08-01658o1849o184910.1107/S1600536809025604tert-Butyl N-{4-methyl-3-[4-(3-pyridyl)pyrimidin-2-yloxy]phenyl}carbamateShi-Gui TangJian-Qiang WangCheng GuoIn the molecule of the title compound, C21H22N4O3, the pyrimidine ring is oriented at dihedral angles of 0.51 (3) and 50.76 (3)° to the pyridine and benzene rings, respectively. In the crystal structure, intermolecular N—H...N hydrogen bonds link the molecules into centrosymmetric dimers, forming R22(24) ring motifs; the dimers are linked by intermolecular C—H...O hydrogen bonds into a two-dimensional network. π–π contacts between the benzene rings and between the pyrimidine and pyridine rings [centroid–centroid distances = 3.891 (1) and 3.646 (1) Å, respectively] may further stabilize the structure. Two weak C—H...π interactions are also present. http://scripts.iucr.org/cgi-bin/paper?S1600536809025604
collection DOAJ
language English
format Article
sources DOAJ
author Shi-Gui Tang
Jian-Qiang Wang
Cheng Guo
spellingShingle Shi-Gui Tang
Jian-Qiang Wang
Cheng Guo
tert-Butyl N-{4-methyl-3-[4-(3-pyridyl)pyrimidin-2-yloxy]phenyl}carbamate
Acta Crystallographica Section E
author_facet Shi-Gui Tang
Jian-Qiang Wang
Cheng Guo
author_sort Shi-Gui Tang
title tert-Butyl N-{4-methyl-3-[4-(3-pyridyl)pyrimidin-2-yloxy]phenyl}carbamate
title_short tert-Butyl N-{4-methyl-3-[4-(3-pyridyl)pyrimidin-2-yloxy]phenyl}carbamate
title_full tert-Butyl N-{4-methyl-3-[4-(3-pyridyl)pyrimidin-2-yloxy]phenyl}carbamate
title_fullStr tert-Butyl N-{4-methyl-3-[4-(3-pyridyl)pyrimidin-2-yloxy]phenyl}carbamate
title_full_unstemmed tert-Butyl N-{4-methyl-3-[4-(3-pyridyl)pyrimidin-2-yloxy]phenyl}carbamate
title_sort tert-butyl n-{4-methyl-3-[4-(3-pyridyl)pyrimidin-2-yloxy]phenyl}carbamate
publisher International Union of Crystallography
series Acta Crystallographica Section E
issn 1600-5368
publishDate 2009-08-01
description In the molecule of the title compound, C21H22N4O3, the pyrimidine ring is oriented at dihedral angles of 0.51 (3) and 50.76 (3)° to the pyridine and benzene rings, respectively. In the crystal structure, intermolecular N—H...N hydrogen bonds link the molecules into centrosymmetric dimers, forming R22(24) ring motifs; the dimers are linked by intermolecular C—H...O hydrogen bonds into a two-dimensional network. π–π contacts between the benzene rings and between the pyrimidine and pyridine rings [centroid–centroid distances = 3.891 (1) and 3.646 (1) Å, respectively] may further stabilize the structure. Two weak C—H...π interactions are also present.
url http://scripts.iucr.org/cgi-bin/paper?S1600536809025604
work_keys_str_mv AT shiguitang tertbutyln4methyl343pyridylpyrimidin2yloxyphenylcarbamate
AT jianqiangwang tertbutyln4methyl343pyridylpyrimidin2yloxyphenylcarbamate
AT chengguo tertbutyln4methyl343pyridylpyrimidin2yloxyphenylcarbamate
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