[μ-2,2,4,4,6,6-Hexakis(3,5-dimethylpyrazol-1-yl)-2λ5,4λ5,6λ5-1,3,5,2,4,6-triazatriphosphinine]bis[bis(nitrato- κ2O,O′)cadmium(II)]

[μ-2,2,4,4,6,6-Hexakis(3,5-dimethylpyrazol-1-yl)-2λ5,4λ5,6λ5-1,3,5,2,4,6-triazatriphosphinine]bis[bis(nitrato- κ2O,O′)cadmium(II)]

The complete title complex, [Cd2(NO3)4(C30H42N15P3)], is generated by crystallographic twofold symmetry, with one P and one N atom of the cyclotriphosphazene ligand located on the rotation axis. The non-planar cyclotriphosphazene ring accommodates two Cd ions, and only four out of six exocylcic pyra...

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Main Authors: Soon W. Lee, Sung Yol Yun
Format: Article
Language:English
Published: International Union of Crystallography 2008-12-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S160053680803585X
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spelling doaj-2d239853d97046f49fb68233b3f5231d2020-11-25T01:38:00ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682008-12-016412m1513m151310.1107/S160053680803585X[μ-2,2,4,4,6,6-Hexakis(3,5-dimethylpyrazol-1-yl)-2λ5,4λ5,6λ5-1,3,5,2,4,6-triazatriphosphinine]bis[bis(nitrato- κ2O,O′)cadmium(II)]Soon W. LeeSung Yol YunThe complete title complex, [Cd2(NO3)4(C30H42N15P3)], is generated by crystallographic twofold symmetry, with one P and one N atom of the cyclotriphosphazene ligand located on the rotation axis. The non-planar cyclotriphosphazene ring accommodates two Cd ions, and only four out of six exocylcic pyrazolyl ligands are bound to the Cd metal atoms. Each of these two symmetry-related Cd atoms is coordinated by two bidentate nitrato ligands, two exocylic pyrazolyl N atoms, and one cyclotriphosphazene N atom.http://scripts.iucr.org/cgi-bin/paper?S160053680803585X
collection DOAJ
language English
format Article
sources DOAJ
author Soon W. Lee
Sung Yol Yun
spellingShingle Soon W. Lee
Sung Yol Yun
[μ-2,2,4,4,6,6-Hexakis(3,5-dimethylpyrazol-1-yl)-2λ5,4λ5,6λ5-1,3,5,2,4,6-triazatriphosphinine]bis[bis(nitrato- κ2O,O′)cadmium(II)]
Acta Crystallographica Section E
author_facet Soon W. Lee
Sung Yol Yun
author_sort Soon W. Lee
title [μ-2,2,4,4,6,6-Hexakis(3,5-dimethylpyrazol-1-yl)-2λ5,4λ5,6λ5-1,3,5,2,4,6-triazatriphosphinine]bis[bis(nitrato- κ2O,O′)cadmium(II)]
title_short [μ-2,2,4,4,6,6-Hexakis(3,5-dimethylpyrazol-1-yl)-2λ5,4λ5,6λ5-1,3,5,2,4,6-triazatriphosphinine]bis[bis(nitrato- κ2O,O′)cadmium(II)]
title_full [μ-2,2,4,4,6,6-Hexakis(3,5-dimethylpyrazol-1-yl)-2λ5,4λ5,6λ5-1,3,5,2,4,6-triazatriphosphinine]bis[bis(nitrato- κ2O,O′)cadmium(II)]
title_fullStr [μ-2,2,4,4,6,6-Hexakis(3,5-dimethylpyrazol-1-yl)-2λ5,4λ5,6λ5-1,3,5,2,4,6-triazatriphosphinine]bis[bis(nitrato- κ2O,O′)cadmium(II)]
title_full_unstemmed [μ-2,2,4,4,6,6-Hexakis(3,5-dimethylpyrazol-1-yl)-2λ5,4λ5,6λ5-1,3,5,2,4,6-triazatriphosphinine]bis[bis(nitrato- κ2O,O′)cadmium(II)]
title_sort [μ-2,2,4,4,6,6-hexakis(3,5-dimethylpyrazol-1-yl)-2λ5,4λ5,6λ5-1,3,5,2,4,6-triazatriphosphinine]bis[bis(nitrato- κ2o,o′)cadmium(ii)]
publisher International Union of Crystallography
series Acta Crystallographica Section E
issn 1600-5368
publishDate 2008-12-01
description The complete title complex, [Cd2(NO3)4(C30H42N15P3)], is generated by crystallographic twofold symmetry, with one P and one N atom of the cyclotriphosphazene ligand located on the rotation axis. The non-planar cyclotriphosphazene ring accommodates two Cd ions, and only four out of six exocylcic pyrazolyl ligands are bound to the Cd metal atoms. Each of these two symmetry-related Cd atoms is coordinated by two bidentate nitrato ligands, two exocylic pyrazolyl N atoms, and one cyclotriphosphazene N atom.
url http://scripts.iucr.org/cgi-bin/paper?S160053680803585X
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AT sungyolyun 956224466hexakis35dimethylpyrazol1yl295554955569555135246triazatriphosphininebisbisnitrato9542oo8242cadmiumii
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