Durability of Blended Cements Made with Reactive Aggregates

• Main Authors: Esperanza Menéndez, Miguel Ángel Sanjuán, Ricardo García-Roves, Cristina Argiz, Hairon Recino
• Format: Article
• Language: English
• Published: MDPI AG 2021-05-01
• Series: Materials
• Subjects: building materials; durability; microstructure; alkali–aggregate reaction (AAR) mitigation; natural pozzolan; coal fly ash
• Online Access: https://www.mdpi.com/1996-1944/14/11/2948

Alkali–silica reaction (ASR) is a swelling reaction that occurs in concrete structures over time between the reactive amorphous siliceous aggregate particles and the hydroxyl ions of the hardened concrete pore solution. The aim of this paper is to assess the effect of pozzolanic Portland cements on the alkali–silica reaction (ASR) evaluated from two different points of view: (i) alkali-silica reaction (ASR) abatement and (ii) climatic change mitigation by clinker reduction, i.e., by depleting its emissions. Open porosity, SEM microscopy, compressive strength and ASR-expansion measurements were performed in mortars made with silica fume, siliceous coal fly ash, natural pozzolan and blast-furnace slag. The main contributions are as follows: (i) the higher the content of reactive silica in the pozzolanic material, the greater the ASR inhibition level; (ii) silica fume and coal fly ash are the best Portland cement constituents for ASR mitigation.