Oscillatory-Precessional Motion of a Rydberg Electron Around a Polar Molecule

• Main Author: Eugene Oks
• Format: Article
• Language: English
• Published: MDPI AG 2020-08-01
• Series: Symmetry
• Subjects: polar molecule; Rydberg electron; classical motion; periodic orbits
• Online Access: https://www.mdpi.com/2073-8994/12/8/1275

We provide a detailed classical description of the oscillatory-precessional motion of an electron in the field of an electric dipole. Specifically, we demonstrate that in the general case of the oscillatory-precessional motion of the electron (the oscillations being in the meridional direction (θ-direction) and the precession being along parallels of latitude (φ-direction)), both the θ-oscillations and the φ-precessions can actually occur on the same time scale—contrary to the statement from the work by another author. We obtain the dependence of φ on θ, the time evolution of the dynamical variable θ, the period T_θ of the θ-oscillations, and the change of the angular variable φ during one half-period of the θ-motion—all in the forms of one-fold integrals in the general case and illustrated it pictorially. We also produce the corresponding explicit analytical expressions for relatively small values of the projection p_φ of the angular momentum on the axis of the electric dipole. We also derive a general condition for this conditionally-periodic motion to become periodic (the trajectory of the electron would become a closed curve) and then provide examples of the values of p_φ for this to happen. Besides, for the particular case of p_φ = 0 we produce an explicit analytical result for the dependence of the time t on θ. For the opposite particular case, where p_φ is equal to its maximum possible value (consistent with the bound motion), we derive an explicit analytical result for the period of the revolution of the electron along the parallel of latitude.