(Pyridin-2-yl)methyl 6-bromo-2-oxo-1-[(pyridin-2-yl)methyl]-1,2-dihydroquinoline-4-carboxylate
In the central dihydroquinoline unit of the title compound, C22H16BrN3O3, the dihydropyridinone and benzene rings are inclined to one another by 2.0 (1)°, while the outer pyridine rings are almost perpendicular to the plane of the dihydroquinoline ring system. The conformation of the molecule is par...
| Main Authors: | , , , , , |
|---|---|
| Format: | Article |
| Language: | English |
| Published: |
International Union of Crystallography
2018-02-01
|
| Series: | IUCrData |
| Subjects: | |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S2414314618002882 |
| id |
doaj-2cba8cabf4624131a79dc4dda401e33a |
|---|---|
| record_format |
Article |
| spelling |
doaj-2cba8cabf4624131a79dc4dda401e33a2020-11-24T22:45:11ZengInternational Union of CrystallographyIUCrData2414-31462018-02-0132x18028810.1107/S2414314618002882sj4158(Pyridin-2-yl)methyl 6-bromo-2-oxo-1-[(pyridin-2-yl)methyl]-1,2-dihydroquinoline-4-carboxylateYassir Filali Baba0Youssef Kandri Rodi1Joel T. Mague2Younes Ouzidan3Fouad Ouazzani Chahdi4El Mokhtar Essassi5Laboratoire de Chimie Organique Appliquée, Faculté des Sciences et Techniques, Université Sidi Mohammed Ben Abdellah, Fès, MoroccoLaboratoire de Chimie Organique Appliquée, Faculté des Sciences et Techniques, Université Sidi Mohammed Ben Abdellah, Fès, MoroccoDepartment of Chemistry, Tulane University, New Orleans, LA 70118, USALaboratoire de Chimie Organique Appliquée, Faculté des Sciences et Techniques, Université Sidi Mohammed Ben Abdellah, Fès, MoroccoLaboratoire de Chimie Organique Appliquée, Faculté des Sciences et Techniques, Université Sidi Mohammed Ben Abdellah, Fès, MoroccoLaboratoire de Chimie Organique Hétérocyclique, Pôle de Compétences Pharmacochimie, Mohammed V University in Rabat, BP 1014, Avenue Ibn Batouta, Rabat, MoroccoIn the central dihydroquinoline unit of the title compound, C22H16BrN3O3, the dihydropyridinone and benzene rings are inclined to one another by 2.0 (1)°, while the outer pyridine rings are almost perpendicular to the plane of the dihydroquinoline ring system. The conformation of the molecule is partially determined by an intramolecular C—H...O hydrogen bond. In the crystal, molecules stack along the b-axis direction through a combination of C—H...N and C—H...O hydrogen bonds and π–π stacking interactions involving the dihydroquinoline units, with a centroid-to-centroid distance of 3.7648 (15) Å.http://scripts.iucr.org/cgi-bin/paper?S2414314618002882crystal structuredihydroquinolinehydrogen bondsπ–π stacking |
| collection |
DOAJ |
| language |
English |
| format |
Article |
| sources |
DOAJ |
| author |
Yassir Filali Baba Youssef Kandri Rodi Joel T. Mague Younes Ouzidan Fouad Ouazzani Chahdi El Mokhtar Essassi |
| spellingShingle |
Yassir Filali Baba Youssef Kandri Rodi Joel T. Mague Younes Ouzidan Fouad Ouazzani Chahdi El Mokhtar Essassi (Pyridin-2-yl)methyl 6-bromo-2-oxo-1-[(pyridin-2-yl)methyl]-1,2-dihydroquinoline-4-carboxylate IUCrData crystal structure dihydroquinoline hydrogen bonds π–π stacking |
| author_facet |
Yassir Filali Baba Youssef Kandri Rodi Joel T. Mague Younes Ouzidan Fouad Ouazzani Chahdi El Mokhtar Essassi |
| author_sort |
Yassir Filali Baba |
| title |
(Pyridin-2-yl)methyl 6-bromo-2-oxo-1-[(pyridin-2-yl)methyl]-1,2-dihydroquinoline-4-carboxylate |
| title_short |
(Pyridin-2-yl)methyl 6-bromo-2-oxo-1-[(pyridin-2-yl)methyl]-1,2-dihydroquinoline-4-carboxylate |
| title_full |
(Pyridin-2-yl)methyl 6-bromo-2-oxo-1-[(pyridin-2-yl)methyl]-1,2-dihydroquinoline-4-carboxylate |
| title_fullStr |
(Pyridin-2-yl)methyl 6-bromo-2-oxo-1-[(pyridin-2-yl)methyl]-1,2-dihydroquinoline-4-carboxylate |
| title_full_unstemmed |
(Pyridin-2-yl)methyl 6-bromo-2-oxo-1-[(pyridin-2-yl)methyl]-1,2-dihydroquinoline-4-carboxylate |
| title_sort |
(pyridin-2-yl)methyl 6-bromo-2-oxo-1-[(pyridin-2-yl)methyl]-1,2-dihydroquinoline-4-carboxylate |
| publisher |
International Union of Crystallography |
| series |
IUCrData |
| issn |
2414-3146 |
| publishDate |
2018-02-01 |
| description |
In the central dihydroquinoline unit of the title compound, C22H16BrN3O3, the dihydropyridinone and benzene rings are inclined to one another by 2.0 (1)°, while the outer pyridine rings are almost perpendicular to the plane of the dihydroquinoline ring system. The conformation of the molecule is partially determined by an intramolecular C—H...O hydrogen bond. In the crystal, molecules stack along the b-axis direction through a combination of C—H...N and C—H...O hydrogen bonds and π–π stacking interactions involving the dihydroquinoline units, with a centroid-to-centroid distance of 3.7648 (15) Å. |
| topic |
crystal structure dihydroquinoline hydrogen bonds π–π stacking |
| url |
http://scripts.iucr.org/cgi-bin/paper?S2414314618002882 |
| work_keys_str_mv |
AT yassirfilalibaba pyridin2ylmethyl6bromo2oxo1pyridin2ylmethyl12dihydroquinoline4carboxylate AT youssefkandrirodi pyridin2ylmethyl6bromo2oxo1pyridin2ylmethyl12dihydroquinoline4carboxylate AT joeltmague pyridin2ylmethyl6bromo2oxo1pyridin2ylmethyl12dihydroquinoline4carboxylate AT younesouzidan pyridin2ylmethyl6bromo2oxo1pyridin2ylmethyl12dihydroquinoline4carboxylate AT fouadouazzanichahdi pyridin2ylmethyl6bromo2oxo1pyridin2ylmethyl12dihydroquinoline4carboxylate AT elmokhtaressassi pyridin2ylmethyl6bromo2oxo1pyridin2ylmethyl12dihydroquinoline4carboxylate |
| _version_ |
1725689651835961344 |