Bis[2-hydroxy-N′-(2-hydroxybenzoyl)benzohydrazitato]dipyridinecadmium(II)

Bis[2-hydroxy-N′-(2-hydroxybenzoyl)benzohydrazitato]dipyridinecadmium(II)

The title complex, [Cd(C14H11N2O4)2(C5H5N)2], exhibits crystallographic twofold symmetry. The CdII atom is located on the twofold rotation axis and reveals a slightly distorted octahedral coordination defined by four atoms (N2O2) from two symmetry-related chelate ligands and two pyridine N atoms. In...

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Main Authors: Yu-Ting Chen, Da-Cheng Li
Format: Article
Language:English
Published: International Union of Crystallography 2008-11-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536808034533
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spelling doaj-2c9aa54d006b4cf7847f4ce806d767012020-11-24T21:25:55ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682008-11-016411m1466m146610.1107/S1600536808034533Bis[2-hydroxy-N′-(2-hydroxybenzoyl)benzohydrazitato]dipyridinecadmium(II)Yu-Ting ChenDa-Cheng LiThe title complex, [Cd(C14H11N2O4)2(C5H5N)2], exhibits crystallographic twofold symmetry. The CdII atom is located on the twofold rotation axis and reveals a slightly distorted octahedral coordination defined by four atoms (N2O2) from two symmetry-related chelate ligands and two pyridine N atoms. Intramolecular O—H...O and N—H...O hydrogen bonds stabilize the molecular conformation while intermolecular O—H...O hydrogen bonding links molecules into a triad, generating a helix along the threefold screw axis.http://scripts.iucr.org/cgi-bin/paper?S1600536808034533
collection DOAJ
language English
format Article
sources DOAJ
author Yu-Ting Chen
Da-Cheng Li
spellingShingle Yu-Ting Chen
Da-Cheng Li
Bis[2-hydroxy-N′-(2-hydroxybenzoyl)benzohydrazitato]dipyridinecadmium(II)
Acta Crystallographica Section E
author_facet Yu-Ting Chen
Da-Cheng Li
author_sort Yu-Ting Chen
title Bis[2-hydroxy-N′-(2-hydroxybenzoyl)benzohydrazitato]dipyridinecadmium(II)
title_short Bis[2-hydroxy-N′-(2-hydroxybenzoyl)benzohydrazitato]dipyridinecadmium(II)
title_full Bis[2-hydroxy-N′-(2-hydroxybenzoyl)benzohydrazitato]dipyridinecadmium(II)
title_fullStr Bis[2-hydroxy-N′-(2-hydroxybenzoyl)benzohydrazitato]dipyridinecadmium(II)
title_full_unstemmed Bis[2-hydroxy-N′-(2-hydroxybenzoyl)benzohydrazitato]dipyridinecadmium(II)
title_sort bis[2-hydroxy-n′-(2-hydroxybenzoyl)benzohydrazitato]dipyridinecadmium(ii)
publisher International Union of Crystallography
series Acta Crystallographica Section E
issn 1600-5368
publishDate 2008-11-01
description The title complex, [Cd(C14H11N2O4)2(C5H5N)2], exhibits crystallographic twofold symmetry. The CdII atom is located on the twofold rotation axis and reveals a slightly distorted octahedral coordination defined by four atoms (N2O2) from two symmetry-related chelate ligands and two pyridine N atoms. Intramolecular O—H...O and N—H...O hydrogen bonds stabilize the molecular conformation while intermolecular O—H...O hydrogen bonding links molecules into a triad, generating a helix along the threefold screw axis.
url http://scripts.iucr.org/cgi-bin/paper?S1600536808034533
work_keys_str_mv AT yutingchen bis2hydroxyn82422hydroxybenzoylbenzohydrazitatodipyridinecadmiumii
AT dachengli bis2hydroxyn82422hydroxybenzoylbenzohydrazitatodipyridinecadmiumii
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