16-[(E)-Benzylidene]-2-hydroxy-12,13-diphenyl-1,11-diazapentacyclo[12.3.1.02,10.03,8.010,14]octadeca-3(8),4,6-triene-9,15-dione

16-[(E)-Benzylidene]-2-hydroxy-12,13-diphenyl-1,11-diazapentacyclo[12.3.1.02,10.03,8.010,14]octadeca-3(8),4,6-triene-9,15-dione

In the title compound, C35H28N2O3, an intramolecular O—H...N hydrogen bonds generates a five-membered ring, producing an S(5) ring motif. The piperidone ring adopts a half-chair conformation and the two pyrrolidine rings adopt an envelope conformation. The dihedral angles formed betwee...

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Main Authors: Raju Suresh Kumar, Hasnah Osman, Mohamed Ashraf Ali, Jia Hao Goh, Hoong-Kun Fun
Format: Article
Language:English
Published: International Union of Crystallography 2010-08-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536810028345
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spelling doaj-2c7018d293b345558fc3b7836a133d9f2020-11-25T01:14:22ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682010-08-01668o2084o208510.1107/S160053681002834516-[(E)-Benzylidene]-2-hydroxy-12,13-diphenyl-1,11-diazapentacyclo[12.3.1.02,10.03,8.010,14]octadeca-3(8),4,6-triene-9,15-dioneRaju Suresh KumarHasnah OsmanMohamed Ashraf AliJia Hao GohHoong-Kun FunIn the title compound, C35H28N2O3, an intramolecular O—H...N hydrogen bonds generates a five-membered ring, producing an S(5) ring motif. The piperidone ring adopts a half-chair conformation and the two pyrrolidine rings adopt an envelope conformation. The dihedral angles formed between adjacent benzene rings are 74.39 (5) and 37.70 (6)°. In the crystal crystal, intermolecular C—H...O hydrogen bonds link molecules into dimers, which are further interconnected into two-dimensional networks parallel to the ac plane by an intermolecular C—H...O hydrogen bond. The crystal structure is consolidated by weak C—H...π interactions. http://scripts.iucr.org/cgi-bin/paper?S1600536810028345
collection DOAJ
language English
format Article
sources DOAJ
author Raju Suresh Kumar
Hasnah Osman
Mohamed Ashraf Ali
Jia Hao Goh
Hoong-Kun Fun
spellingShingle Raju Suresh Kumar
Hasnah Osman
Mohamed Ashraf Ali
Jia Hao Goh
Hoong-Kun Fun
16-[(E)-Benzylidene]-2-hydroxy-12,13-diphenyl-1,11-diazapentacyclo[12.3.1.02,10.03,8.010,14]octadeca-3(8),4,6-triene-9,15-dione
Acta Crystallographica Section E
author_facet Raju Suresh Kumar
Hasnah Osman
Mohamed Ashraf Ali
Jia Hao Goh
Hoong-Kun Fun
author_sort Raju Suresh Kumar
title 16-[(E)-Benzylidene]-2-hydroxy-12,13-diphenyl-1,11-diazapentacyclo[12.3.1.02,10.03,8.010,14]octadeca-3(8),4,6-triene-9,15-dione
title_short 16-[(E)-Benzylidene]-2-hydroxy-12,13-diphenyl-1,11-diazapentacyclo[12.3.1.02,10.03,8.010,14]octadeca-3(8),4,6-triene-9,15-dione
title_full 16-[(E)-Benzylidene]-2-hydroxy-12,13-diphenyl-1,11-diazapentacyclo[12.3.1.02,10.03,8.010,14]octadeca-3(8),4,6-triene-9,15-dione
title_fullStr 16-[(E)-Benzylidene]-2-hydroxy-12,13-diphenyl-1,11-diazapentacyclo[12.3.1.02,10.03,8.010,14]octadeca-3(8),4,6-triene-9,15-dione
title_full_unstemmed 16-[(E)-Benzylidene]-2-hydroxy-12,13-diphenyl-1,11-diazapentacyclo[12.3.1.02,10.03,8.010,14]octadeca-3(8),4,6-triene-9,15-dione
title_sort 16-[(e)-benzylidene]-2-hydroxy-12,13-diphenyl-1,11-diazapentacyclo[12.3.1.02,10.03,8.010,14]octadeca-3(8),4,6-triene-9,15-dione
publisher International Union of Crystallography
series Acta Crystallographica Section E
issn 1600-5368
publishDate 2010-08-01
description In the title compound, C35H28N2O3, an intramolecular O—H...N hydrogen bonds generates a five-membered ring, producing an S(5) ring motif. The piperidone ring adopts a half-chair conformation and the two pyrrolidine rings adopt an envelope conformation. The dihedral angles formed between adjacent benzene rings are 74.39 (5) and 37.70 (6)°. In the crystal crystal, intermolecular C—H...O hydrogen bonds link molecules into dimers, which are further interconnected into two-dimensional networks parallel to the ac plane by an intermolecular C—H...O hydrogen bond. The crystal structure is consolidated by weak C—H...π interactions.
url http://scripts.iucr.org/cgi-bin/paper?S1600536810028345
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AT mohamedashrafali 16ebenzylidene2hydroxy1213diphenyl111diazapentacyclo1231021003801014octadeca3846triene915dione
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