Response surface methodology as a statistical tool for optimization of removal of chromium (VI) from aqueous solution by Teff (Eragrostis teff) husk activated carbon

Abstract Recently, rapid industrialization leads to excessive release of heavy metals such as Cr(VI) in the environment. Exposure to chromium (VI) can cause kidney and liver damage, depressed immune systems, and a variety of cancers. Therefore, treatment of Cr(VI) containing wastewater is mandatory....

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Main Authors: Tsegaye Adane, Daniel Haile, Awrajaw Dessie, Yohannes Abebe, Henok Dagne
Format: Article
Language:English
Published: SpringerOpen 2019-12-01
Series:Applied Water Science
Subjects:
Online Access:https://doi.org/10.1007/s13201-019-1120-8
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spelling doaj-2b9489c824db499e811d4738eed994f82020-12-20T12:37:59ZengSpringerOpenApplied Water Science2190-54872190-54952019-12-0110111310.1007/s13201-019-1120-8Response surface methodology as a statistical tool for optimization of removal of chromium (VI) from aqueous solution by Teff (Eragrostis teff) husk activated carbonTsegaye Adane0Daniel Haile1Awrajaw Dessie2Yohannes Abebe3Henok Dagne4Department of Environmental and Occupational Health and Safety, Institute of Public Health, College of Medicine and Health Sciences, University of GondarDepartment of Environmental and Occupational Health and Safety, Institute of Public Health, College of Medicine and Health Sciences, University of GondarDepartment of Environmental and Occupational Health and Safety, Institute of Public Health, College of Medicine and Health Sciences, University of GondarDepartment of Chemistry, College of Natural and Computational Sciences, University of GondarDepartment of Environmental and Occupational Health and Safety, Institute of Public Health, College of Medicine and Health Sciences, University of GondarAbstract Recently, rapid industrialization leads to excessive release of heavy metals such as Cr(VI) in the environment. Exposure to chromium (VI) can cause kidney and liver damage, depressed immune systems, and a variety of cancers. Therefore, treatment of Cr(VI) containing wastewater is mandatory. This study aims to optimize the removal of Cr(VI) from aqueous solution using locally available Teff husk activated carbon adsorbent. The laboratory-based study was conducted on the optimization of Cr(VI) removal efficiency of Teff husk activated carbon from aqueous solution. A central composite design was used to examine the effect of the interaction of process parameters and to optimize the process using Design Expert version 7.0 software. The optimized removal efficiency of Teff husk activated carbon (95.597%) was achieved at 1.92 pH, 87.83 mg/L initial concentration, 20.22 g/L adsorbent dose, and 2.07 H contact time. The adsorption of Cr(VI) on Teff husk activated carbon was found to be best fitted with pseudo-second-order kinetics and Langmuir isotherm model of the adsorption. Teff husk activated carbon can be used as an efficient adsorbent for removal of chromium (VI) from contaminated water. Column adsorption needs to be studied in the future.https://doi.org/10.1007/s13201-019-1120-8Batch adsorptionChromium (VI)Teff husk activated carbonCentral composite design
collection DOAJ
language English
format Article
sources DOAJ
author Tsegaye Adane
Daniel Haile
Awrajaw Dessie
Yohannes Abebe
Henok Dagne
spellingShingle Tsegaye Adane
Daniel Haile
Awrajaw Dessie
Yohannes Abebe
Henok Dagne
Response surface methodology as a statistical tool for optimization of removal of chromium (VI) from aqueous solution by Teff (Eragrostis teff) husk activated carbon
Applied Water Science
Batch adsorption
Chromium (VI)
Teff husk activated carbon
Central composite design
author_facet Tsegaye Adane
Daniel Haile
Awrajaw Dessie
Yohannes Abebe
Henok Dagne
author_sort Tsegaye Adane
title Response surface methodology as a statistical tool for optimization of removal of chromium (VI) from aqueous solution by Teff (Eragrostis teff) husk activated carbon
title_short Response surface methodology as a statistical tool for optimization of removal of chromium (VI) from aqueous solution by Teff (Eragrostis teff) husk activated carbon
title_full Response surface methodology as a statistical tool for optimization of removal of chromium (VI) from aqueous solution by Teff (Eragrostis teff) husk activated carbon
title_fullStr Response surface methodology as a statistical tool for optimization of removal of chromium (VI) from aqueous solution by Teff (Eragrostis teff) husk activated carbon
title_full_unstemmed Response surface methodology as a statistical tool for optimization of removal of chromium (VI) from aqueous solution by Teff (Eragrostis teff) husk activated carbon
title_sort response surface methodology as a statistical tool for optimization of removal of chromium (vi) from aqueous solution by teff (eragrostis teff) husk activated carbon
publisher SpringerOpen
series Applied Water Science
issn 2190-5487
2190-5495
publishDate 2019-12-01
description Abstract Recently, rapid industrialization leads to excessive release of heavy metals such as Cr(VI) in the environment. Exposure to chromium (VI) can cause kidney and liver damage, depressed immune systems, and a variety of cancers. Therefore, treatment of Cr(VI) containing wastewater is mandatory. This study aims to optimize the removal of Cr(VI) from aqueous solution using locally available Teff husk activated carbon adsorbent. The laboratory-based study was conducted on the optimization of Cr(VI) removal efficiency of Teff husk activated carbon from aqueous solution. A central composite design was used to examine the effect of the interaction of process parameters and to optimize the process using Design Expert version 7.0 software. The optimized removal efficiency of Teff husk activated carbon (95.597%) was achieved at 1.92 pH, 87.83 mg/L initial concentration, 20.22 g/L adsorbent dose, and 2.07 H contact time. The adsorption of Cr(VI) on Teff husk activated carbon was found to be best fitted with pseudo-second-order kinetics and Langmuir isotherm model of the adsorption. Teff husk activated carbon can be used as an efficient adsorbent for removal of chromium (VI) from contaminated water. Column adsorption needs to be studied in the future.
topic Batch adsorption
Chromium (VI)
Teff husk activated carbon
Central composite design
url https://doi.org/10.1007/s13201-019-1120-8
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