Selectivity and efficiency of pyrene attachment to alkanes induced by broadband X-rays
Bombardment of pyrene-doped n-heneicosane (C21H44) in its orthorhombic solid phase with <1.3> MeV broadband X-rays results in the formation of both mono- and di-heneicosylpyrenes, whereas the same dose in liquid cyclohexane yields only monosubstituted pyrene. In both cases, the reaction effici...
Main Authors: | GERALD O. BROWN, NOEL A. GUARDALA, JACK L. PRICE, RICHARD G. WEISS |
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Format: | Article |
Language: | English |
Published: |
Academia Brasileira de Ciências
2003-03-01
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Series: | Anais da Academia Brasileira de Ciências |
Subjects: | |
Online Access: | http://www.scielo.br/scielo.php?script=sci_arttext&pid=S0001-37652003000100005 |
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