2-Vinylpyridine–tris(pentafluorophenyl)borane hexane monosolvate

2-Vinylpyridine–tris(pentafluorophenyl)borane hexane monosolvate

The title compound, C7H7N·B(C6F5)3·C6H14, was obtained by the stoichiometric reaction of 2-vinylpyridine and tris(pentafluorophenyl)borane in toluene. The formed adduct exhibits a restricted rotation along the B—N bond resulting in an asymmetry, which can be a...

Full description

Bibliographic Details
Main Authors: Marcus Klahn, Anke Spannenberg, Uwe Rosenthal
Format: Article
Language:English
Published: International Union of Crystallography 2012-04-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536812013153
id doaj-2b24df0eadcf41bcb73d2d889606091d
record_format Article
spelling doaj-2b24df0eadcf41bcb73d2d889606091d2020-11-25T01:35:55ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682012-04-01684o1261o126110.1107/S16005368120131532-Vinylpyridine–tris(pentafluorophenyl)borane hexane monosolvateMarcus KlahnAnke SpannenbergUwe RosenthalThe title compound, C7H7N·B(C6F5)3·C6H14, was obtained by the stoichiometric reaction of 2-vinylpyridine and tris(pentafluorophenyl)borane in toluene. The formed adduct exhibits a restricted rotation along the B—N bond resulting in an asymmetry, which can be also observed in the 19F NMR spectra. The B—N distance is equivalent to the distances found for 2-methylpyridine and 2-ethylpyridine B(C6F5)3 adducts. For the final refinement, the contributions of disordered solvent molecules were removed from the diffraction data with SQUEEZE in PLATON [van der Sluis & Spek (1990). Acta Cryst. A46, 194–201; Spek (2009). Acta Cryst. D65, 148–155].http://scripts.iucr.org/cgi-bin/paper?S1600536812013153
collection DOAJ
language English
format Article
sources DOAJ
author Marcus Klahn
Anke Spannenberg
Uwe Rosenthal
spellingShingle Marcus Klahn
Anke Spannenberg
Uwe Rosenthal
2-Vinylpyridine–tris(pentafluorophenyl)borane hexane monosolvate
Acta Crystallographica Section E
author_facet Marcus Klahn
Anke Spannenberg
Uwe Rosenthal
author_sort Marcus Klahn
title 2-Vinylpyridine–tris(pentafluorophenyl)borane hexane monosolvate
title_short 2-Vinylpyridine–tris(pentafluorophenyl)borane hexane monosolvate
title_full 2-Vinylpyridine–tris(pentafluorophenyl)borane hexane monosolvate
title_fullStr 2-Vinylpyridine–tris(pentafluorophenyl)borane hexane monosolvate
title_full_unstemmed 2-Vinylpyridine–tris(pentafluorophenyl)borane hexane monosolvate
title_sort 2-vinylpyridine–tris(pentafluorophenyl)borane hexane monosolvate
publisher International Union of Crystallography
series Acta Crystallographica Section E
issn 1600-5368
publishDate 2012-04-01
description The title compound, C7H7N·B(C6F5)3·C6H14, was obtained by the stoichiometric reaction of 2-vinylpyridine and tris(pentafluorophenyl)borane in toluene. The formed adduct exhibits a restricted rotation along the B—N bond resulting in an asymmetry, which can be also observed in the 19F NMR spectra. The B—N distance is equivalent to the distances found for 2-methylpyridine and 2-ethylpyridine B(C6F5)3 adducts. For the final refinement, the contributions of disordered solvent molecules were removed from the diffraction data with SQUEEZE in PLATON [van der Sluis & Spek (1990). Acta Cryst. A46, 194–201; Spek (2009). Acta Cryst. D65, 148–155].
url http://scripts.iucr.org/cgi-bin/paper?S1600536812013153
work_keys_str_mv AT marcusklahn 2vinylpyridineamp8211trispentafluorophenylboranehexanemonosolvate
AT ankespannenberg 2vinylpyridineamp8211trispentafluorophenylboranehexanemonosolvate
AT uwerosenthal 2vinylpyridineamp8211trispentafluorophenylboranehexanemonosolvate
_version_ 1725065422781284352

Similar Items