Synthesis and characterization of the coordination polymer [(THF)K(μ-OPri)2Al(μ-OPri)2]n
Reaction of [Al(OPri)3] with K(OPri), in 1:1 molar ratio in refluxing anhydrous tetrahydrofuran yields a polymeric complex [(THF)K(μ-OPri)2Al(μ-OPri)2]n. The complex is characterized by spectroscopic studies and single crystal X-raydiffraction analysis.
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Online Access: | https://doi.org/10.1515/mgmc-2018-0004 |
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doaj-2aae3e73d06f4078bee5d089f00a29122021-10-02T19:12:38ZengDe GruyterMain Group Metal Chemistry0792-12412191-02192018-05-01411-2434610.1515/mgmc-2018-0004Synthesis and characterization of the coordination polymer [(THF)K(μ-OPri)2Al(μ-OPri)2]nGopal Ram0Sharma Nikita1Nagar Meena2Chaudhary Archana3Mobin Shaikh M.4Bohra Rakesh5Department of Chemistry, University of Rajasthan, Jaipur 302004, Rajasthan, IndiaDepartment of Chemistry, Government Girls College, Chomu, Jaipur, Rajasthan, IndiaDepartment of Chemistry, University of Rajasthan, Jaipur 302004, Rajasthan, IndiaDiscipline of Chemistry, School of Basic Sciences, Indian Institute of Technology Indore, Khandwa Road, Indore 452017, IndiaDiscipline of Chemistry, School of Basic Sciences, Indian Institute of Technology Indore, Khandwa Road, Indore 452017, IndiaDepartment of Chemistry, University of Rajasthan, Jaipur 302004, Rajasthan, IndiaReaction of [Al(OPri)3] with K(OPri), in 1:1 molar ratio in refluxing anhydrous tetrahydrofuran yields a polymeric complex [(THF)K(μ-OPri)2Al(μ-OPri)2]n. The complex is characterized by spectroscopic studies and single crystal X-raydiffraction analysis.https://doi.org/10.1515/mgmc-2018-0004aminopyramidienecatalytic activity[k{al(opri)4}][(thf)k(μ-opri)2al(μ-opri)2]nx-ray structure |
collection |
DOAJ |
language |
English |
format |
Article |
sources |
DOAJ |
author |
Gopal Ram Sharma Nikita Nagar Meena Chaudhary Archana Mobin Shaikh M. Bohra Rakesh |
spellingShingle |
Gopal Ram Sharma Nikita Nagar Meena Chaudhary Archana Mobin Shaikh M. Bohra Rakesh Synthesis and characterization of the coordination polymer [(THF)K(μ-OPri)2Al(μ-OPri)2]n Main Group Metal Chemistry aminopyramidiene catalytic activity [k{al(opri)4}] [(thf)k(μ-opri)2al(μ-opri)2]n x-ray structure |
author_facet |
Gopal Ram Sharma Nikita Nagar Meena Chaudhary Archana Mobin Shaikh M. Bohra Rakesh |
author_sort |
Gopal Ram |
title |
Synthesis and characterization of the coordination polymer [(THF)K(μ-OPri)2Al(μ-OPri)2]n |
title_short |
Synthesis and characterization of the coordination polymer [(THF)K(μ-OPri)2Al(μ-OPri)2]n |
title_full |
Synthesis and characterization of the coordination polymer [(THF)K(μ-OPri)2Al(μ-OPri)2]n |
title_fullStr |
Synthesis and characterization of the coordination polymer [(THF)K(μ-OPri)2Al(μ-OPri)2]n |
title_full_unstemmed |
Synthesis and characterization of the coordination polymer [(THF)K(μ-OPri)2Al(μ-OPri)2]n |
title_sort |
synthesis and characterization of the coordination polymer [(thf)k(μ-opri)2al(μ-opri)2]n |
publisher |
De Gruyter |
series |
Main Group Metal Chemistry |
issn |
0792-1241 2191-0219 |
publishDate |
2018-05-01 |
description |
Reaction of [Al(OPri)3] with K(OPri), in 1:1 molar ratio in refluxing anhydrous tetrahydrofuran yields a polymeric complex [(THF)K(μ-OPri)2Al(μ-OPri)2]n. The complex is characterized by spectroscopic studies and single crystal X-raydiffraction analysis. |
topic |
aminopyramidiene catalytic activity [k{al(opri)4}] [(thf)k(μ-opri)2al(μ-opri)2]n x-ray structure |
url |
https://doi.org/10.1515/mgmc-2018-0004 |
work_keys_str_mv |
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1716847797074919424 |