Synthesis and characterization of the coordination polymer [(THF)K(μ-OPri)2Al(μ-OPri)2]n

Reaction of [Al(OPri)3] with K(OPri), in 1:1 molar ratio in refluxing anhydrous tetrahydrofuran yields a polymeric complex [(THF)K(μ-OPri)2Al(μ-OPri)2]n. The complex is characterized by spectroscopic studies and single crystal X-raydiffraction analysis.

Bibliographic Details
Main Authors: Gopal Ram, Sharma Nikita, Nagar Meena, Chaudhary Archana, Mobin Shaikh M., Bohra Rakesh
Format: Article
Language:English
Published: De Gruyter 2018-05-01
Series:Main Group Metal Chemistry
Subjects:
Online Access:https://doi.org/10.1515/mgmc-2018-0004
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spelling doaj-2aae3e73d06f4078bee5d089f00a29122021-10-02T19:12:38ZengDe GruyterMain Group Metal Chemistry0792-12412191-02192018-05-01411-2434610.1515/mgmc-2018-0004Synthesis and characterization of the coordination polymer [(THF)K(μ-OPri)2Al(μ-OPri)2]nGopal Ram0Sharma Nikita1Nagar Meena2Chaudhary Archana3Mobin Shaikh M.4Bohra Rakesh5Department of Chemistry, University of Rajasthan, Jaipur 302004, Rajasthan, IndiaDepartment of Chemistry, Government Girls College, Chomu, Jaipur, Rajasthan, IndiaDepartment of Chemistry, University of Rajasthan, Jaipur 302004, Rajasthan, IndiaDiscipline of Chemistry, School of Basic Sciences, Indian Institute of Technology Indore, Khandwa Road, Indore 452017, IndiaDiscipline of Chemistry, School of Basic Sciences, Indian Institute of Technology Indore, Khandwa Road, Indore 452017, IndiaDepartment of Chemistry, University of Rajasthan, Jaipur 302004, Rajasthan, IndiaReaction of [Al(OPri)3] with K(OPri), in 1:1 molar ratio in refluxing anhydrous tetrahydrofuran yields a polymeric complex [(THF)K(μ-OPri)2Al(μ-OPri)2]n. The complex is characterized by spectroscopic studies and single crystal X-raydiffraction analysis.https://doi.org/10.1515/mgmc-2018-0004aminopyramidienecatalytic activity[k{al(opri)4}][(thf)k(μ-opri)2al(μ-opri)2]nx-ray structure
collection DOAJ
language English
format Article
sources DOAJ
author Gopal Ram
Sharma Nikita
Nagar Meena
Chaudhary Archana
Mobin Shaikh M.
Bohra Rakesh
spellingShingle Gopal Ram
Sharma Nikita
Nagar Meena
Chaudhary Archana
Mobin Shaikh M.
Bohra Rakesh
Synthesis and characterization of the coordination polymer [(THF)K(μ-OPri)2Al(μ-OPri)2]n
Main Group Metal Chemistry
aminopyramidiene
catalytic activity
[k{al(opri)4}]
[(thf)k(μ-opri)2al(μ-opri)2]n
x-ray structure
author_facet Gopal Ram
Sharma Nikita
Nagar Meena
Chaudhary Archana
Mobin Shaikh M.
Bohra Rakesh
author_sort Gopal Ram
title Synthesis and characterization of the coordination polymer [(THF)K(μ-OPri)2Al(μ-OPri)2]n
title_short Synthesis and characterization of the coordination polymer [(THF)K(μ-OPri)2Al(μ-OPri)2]n
title_full Synthesis and characterization of the coordination polymer [(THF)K(μ-OPri)2Al(μ-OPri)2]n
title_fullStr Synthesis and characterization of the coordination polymer [(THF)K(μ-OPri)2Al(μ-OPri)2]n
title_full_unstemmed Synthesis and characterization of the coordination polymer [(THF)K(μ-OPri)2Al(μ-OPri)2]n
title_sort synthesis and characterization of the coordination polymer [(thf)k(μ-opri)2al(μ-opri)2]n
publisher De Gruyter
series Main Group Metal Chemistry
issn 0792-1241
2191-0219
publishDate 2018-05-01
description Reaction of [Al(OPri)3] with K(OPri), in 1:1 molar ratio in refluxing anhydrous tetrahydrofuran yields a polymeric complex [(THF)K(μ-OPri)2Al(μ-OPri)2]n. The complex is characterized by spectroscopic studies and single crystal X-raydiffraction analysis.
topic aminopyramidiene
catalytic activity
[k{al(opri)4}]
[(thf)k(μ-opri)2al(μ-opri)2]n
x-ray structure
url https://doi.org/10.1515/mgmc-2018-0004
work_keys_str_mv AT gopalram synthesisandcharacterizationofthecoordinationpolymerthfkmopri2almopri2n
AT sharmanikita synthesisandcharacterizationofthecoordinationpolymerthfkmopri2almopri2n
AT nagarmeena synthesisandcharacterizationofthecoordinationpolymerthfkmopri2almopri2n
AT chaudharyarchana synthesisandcharacterizationofthecoordinationpolymerthfkmopri2almopri2n
AT mobinshaikhm synthesisandcharacterizationofthecoordinationpolymerthfkmopri2almopri2n
AT bohrarakesh synthesisandcharacterizationofthecoordinationpolymerthfkmopri2almopri2n
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