7-Methoxy-1-{[(Z)-2-nitrophenylimino](phenyl)methyl}-2-naphthol chloroform monosolvate

7-Methoxy-1-{[(Z)-2-nitrophenylimino](phenyl)methyl}-2-naphthol chloroform monosolvate

In the title compound, C24H18N2O4·CHCl3, the phenyl and benzene rings make a dihedral angle of 38.60 (9)° and connect in an orientation almost perpendicular to the naphthalene ring system at dihedral angles of 78.73 (8) and 81.20 (7...

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Main Authors: Noriyuki Yonezawa, Akiko Okamoto, Atsushi Nagasawa
Format: Article
Language:English
Published: International Union of Crystallography 2010-12-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536810048002
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spelling doaj-2aa35149a3bc4ab791c2b5a10897fe4d2020-11-25T00:12:32ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682010-12-016612o3283o328310.1107/S16005368100480027-Methoxy-1-{[(Z)-2-nitrophenylimino](phenyl)methyl}-2-naphthol chloroform monosolvateNoriyuki YonezawaAkiko OkamotoAtsushi NagasawaIn the title compound, C24H18N2O4·CHCl3, the phenyl and benzene rings make a dihedral angle of 38.60 (9)° and connect in an orientation almost perpendicular to the naphthalene ring system at dihedral angles of 78.73 (8) and 81.20 (7)°. The molecule has a Z configuration about the C=N bond. In the crystal, molecules are linked by intermolecular O—H...N=C hydrogen bonds between the imino moiety and hydroxy groups. Intermolecular C—Cl...C interactions between Cl atoms of the CHCl3 molecule and C atoms of the naphthalene rings are also present [Cl...C = 3.353 (2) and 3.326 (19) Å]. The nitro group and the chloroform solvent molecule are disordered over two positions with site occupancies of 0.884 (4) and 0.116 (4). http://scripts.iucr.org/cgi-bin/paper?S1600536810048002
collection DOAJ
language English
format Article
sources DOAJ
author Noriyuki Yonezawa
Akiko Okamoto
Atsushi Nagasawa
spellingShingle Noriyuki Yonezawa
Akiko Okamoto
Atsushi Nagasawa
7-Methoxy-1-{[(Z)-2-nitrophenylimino](phenyl)methyl}-2-naphthol chloroform monosolvate
Acta Crystallographica Section E
author_facet Noriyuki Yonezawa
Akiko Okamoto
Atsushi Nagasawa
author_sort Noriyuki Yonezawa
title 7-Methoxy-1-{[(Z)-2-nitrophenylimino](phenyl)methyl}-2-naphthol chloroform monosolvate
title_short 7-Methoxy-1-{[(Z)-2-nitrophenylimino](phenyl)methyl}-2-naphthol chloroform monosolvate
title_full 7-Methoxy-1-{[(Z)-2-nitrophenylimino](phenyl)methyl}-2-naphthol chloroform monosolvate
title_fullStr 7-Methoxy-1-{[(Z)-2-nitrophenylimino](phenyl)methyl}-2-naphthol chloroform monosolvate
title_full_unstemmed 7-Methoxy-1-{[(Z)-2-nitrophenylimino](phenyl)methyl}-2-naphthol chloroform monosolvate
title_sort 7-methoxy-1-{[(z)-2-nitrophenylimino](phenyl)methyl}-2-naphthol chloroform monosolvate
publisher International Union of Crystallography
series Acta Crystallographica Section E
issn 1600-5368
publishDate 2010-12-01
description In the title compound, C24H18N2O4·CHCl3, the phenyl and benzene rings make a dihedral angle of 38.60 (9)° and connect in an orientation almost perpendicular to the naphthalene ring system at dihedral angles of 78.73 (8) and 81.20 (7)°. The molecule has a Z configuration about the C=N bond. In the crystal, molecules are linked by intermolecular O—H...N=C hydrogen bonds between the imino moiety and hydroxy groups. Intermolecular C—Cl...C interactions between Cl atoms of the CHCl3 molecule and C atoms of the naphthalene rings are also present [Cl...C = 3.353 (2) and 3.326 (19) Å]. The nitro group and the chloroform solvent molecule are disordered over two positions with site occupancies of 0.884 (4) and 0.116 (4).
url http://scripts.iucr.org/cgi-bin/paper?S1600536810048002
work_keys_str_mv AT noriyukiyonezawa 7methoxy1z2nitrophenyliminophenylmethyl2naphtholchloroformmonosolvate
AT akikookamoto 7methoxy1z2nitrophenyliminophenylmethyl2naphtholchloroformmonosolvate
AT atsushinagasawa 7methoxy1z2nitrophenyliminophenylmethyl2naphtholchloroformmonosolvate
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