Desenvolvimento do método de extração sólido-líquido com partição em baixa temperatura para determinação de inseticidas em grãos de milho ozonizados

• Main Authors: Romenique da Silva de Freitas, Maria Eliana Lopes Ribeiro de Queiroz, Lêda Rita D'Antonino Faroni, Fernanda Fernandes Heleno, Vanessa Vaz de Moura
• Format: Article
• Language: English
• Published: Sociedade Brasileira de Química 2014-04-01
• Series: Química Nova
• Subjects: bifenthrin; pirimiphos-methyl; gas chromatography
• Online Access: http://www.scielo.br/scielo.php?script=sci_arttext&pid=S0100-40422014000200008&lng=en&tlng=en

The objective of this study was to optimize and validate a solid-liquid extraction method with low-temperature partitioning (SLE/LTP) for the analysis of pesticides. This method was coupled with gas chromatography (GC/ECD) and used to evaluate the degradation of bifenthrin and pirimiphos-methyl in maize grains on exposure to ozone. The optimized SLE/LTP-GC/ECD method is simple, effective and consumes low quantities of the solvent. It can be routinely used for the determination of bifenthrin and pirimiphos-methyl in maize samples. The use of this method of analysis determined that the levels of the insecticides in maize grains were reduced on exposure of the grains to the ozone gas. The observed reduction in the levels of insecticide was directly proportional to the increase in the concentration of the ozone gas.