Crystal structure of ethyl (1RS,6SR)-4-(2-methyl-1H-imidazol-4-yl)-2-oxo-6-(2,3,5-trichlorophenyl)cyclohex-3-ene-1-carboxylate

The title compound, C19H17Cl3N2O3, has been prepared in a cyclocondensation reaction between 2,3,5-trichlorobenzaldehye and 4-acetyl-2-methyl-1H-imidazole. The cyclohexenone ring adopts an envelope conformation with the C atom substituted by the trichlorophenyl ring as the flap. The mutually trans e...

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Main Authors:	Billava J. Mohan, Balladka K. Sarojini, Hemmige S. Yathirajan, Ravindranath Rathore, Christopher Glidewell
Format:	Article
Language:	English
Published:	International Union of Crystallography 2016-01-01
Series:	Acta Crystallographica Section E: Crystallographic Communications
Subjects:	crystal structure cyclocondensation reaction molecular stereochemistry molecular conformation hydrogen bonding
Online Access:	http://scripts.iucr.org/cgi-bin/paper?S2056989015023245

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spelling	doaj-2a77a11d573946b69bcf3c53b9f5b7432020-11-24T22:33:32ZengInternational Union of CrystallographyActa Crystallographica Section E: Crystallographic Communications2056-98902016-01-01721313410.1107/S2056989015023245su5251Crystal structure of ethyl (1RS,6SR)-4-(2-methyl-1H-imidazol-4-yl)-2-oxo-6-(2,3,5-trichlorophenyl)cyclohex-3-ene-1-carboxylateBillava J. Mohan0Balladka K. Sarojini1Hemmige S. Yathirajan2Ravindranath Rathore3Christopher Glidewell4Department of Chemistry, P.A. College of Engineering, Mangaluru 574 153, IndiaDepartment of Studies in Industrial Chemistry, Mangalore University, Mangalagangothri 574 199, IndiaDepartment of Studies in Chemistry, University of Mysore, Manasagangotri, Mysuru 570 006, IndiaDepartment of Biotechnology, Dayananda Sagar College of Engineering, Bengaluru 560 078, IndiaSchool of Chemistry, University of St Andrews, Fife KY16 9ST, ScotlandThe title compound, C19H17Cl3N2O3, has been prepared in a cyclocondensation reaction between 2,3,5-trichlorobenzaldehye and 4-acetyl-2-methyl-1H-imidazole. The cyclohexenone ring adopts an envelope conformation with the C atom substituted by the trichlorophenyl ring as the flap. The mutually trans ester and aryl substituents both occupy equatorial sites. In the crystal, a combination of N—H...O and C—H...N hydrogen bonds links the molecules into ribbons of edge-fused centrosymmetric rings, which enclose R22(14) and R44(16) alternate ring motifs, propagating along the b-axis direction.http://scripts.iucr.org/cgi-bin/paper?S2056989015023245crystal structurecyclocondensation reactionmolecular stereochemistrymolecular conformationhydrogen bonding
collection	DOAJ
language	English
format	Article
sources	DOAJ
author	Billava J. Mohan Balladka K. Sarojini Hemmige S. Yathirajan Ravindranath Rathore Christopher Glidewell
spellingShingle	Billava J. Mohan Balladka K. Sarojini Hemmige S. Yathirajan Ravindranath Rathore Christopher Glidewell Crystal structure of ethyl (1RS,6SR)-4-(2-methyl-1H-imidazol-4-yl)-2-oxo-6-(2,3,5-trichlorophenyl)cyclohex-3-ene-1-carboxylate Acta Crystallographica Section E: Crystallographic Communications crystal structure cyclocondensation reaction molecular stereochemistry molecular conformation hydrogen bonding
author_facet	Billava J. Mohan Balladka K. Sarojini Hemmige S. Yathirajan Ravindranath Rathore Christopher Glidewell
author_sort	Billava J. Mohan
title	Crystal structure of ethyl (1RS,6SR)-4-(2-methyl-1H-imidazol-4-yl)-2-oxo-6-(2,3,5-trichlorophenyl)cyclohex-3-ene-1-carboxylate
title_short	Crystal structure of ethyl (1RS,6SR)-4-(2-methyl-1H-imidazol-4-yl)-2-oxo-6-(2,3,5-trichlorophenyl)cyclohex-3-ene-1-carboxylate
title_full	Crystal structure of ethyl (1RS,6SR)-4-(2-methyl-1H-imidazol-4-yl)-2-oxo-6-(2,3,5-trichlorophenyl)cyclohex-3-ene-1-carboxylate
title_fullStr	Crystal structure of ethyl (1RS,6SR)-4-(2-methyl-1H-imidazol-4-yl)-2-oxo-6-(2,3,5-trichlorophenyl)cyclohex-3-ene-1-carboxylate
title_full_unstemmed	Crystal structure of ethyl (1RS,6SR)-4-(2-methyl-1H-imidazol-4-yl)-2-oxo-6-(2,3,5-trichlorophenyl)cyclohex-3-ene-1-carboxylate
title_sort	crystal structure of ethyl (1rs,6sr)-4-(2-methyl-1h-imidazol-4-yl)-2-oxo-6-(2,3,5-trichlorophenyl)cyclohex-3-ene-1-carboxylate
publisher	International Union of Crystallography
series	Acta Crystallographica Section E: Crystallographic Communications
issn	2056-9890
publishDate	2016-01-01
description	The title compound, C19H17Cl3N2O3, has been prepared in a cyclocondensation reaction between 2,3,5-trichlorobenzaldehye and 4-acetyl-2-methyl-1H-imidazole. The cyclohexenone ring adopts an envelope conformation with the C atom substituted by the trichlorophenyl ring as the flap. The mutually trans ester and aryl substituents both occupy equatorial sites. In the crystal, a combination of N—H...O and C—H...N hydrogen bonds links the molecules into ribbons of edge-fused centrosymmetric rings, which enclose R22(14) and R44(16) alternate ring motifs, propagating along the b-axis direction.
topic	crystal structure cyclocondensation reaction molecular stereochemistry molecular conformation hydrogen bonding
url	http://scripts.iucr.org/cgi-bin/paper?S2056989015023245
work_keys_str_mv	AT billavajmohan crystalstructureofethyl1rs6sr42methyl1himidazol4yl2oxo6235trichlorophenylcyclohex3ene1carboxylate AT balladkaksarojini crystalstructureofethyl1rs6sr42methyl1himidazol4yl2oxo6235trichlorophenylcyclohex3ene1carboxylate AT hemmigesyathirajan crystalstructureofethyl1rs6sr42methyl1himidazol4yl2oxo6235trichlorophenylcyclohex3ene1carboxylate AT ravindranathrathore crystalstructureofethyl1rs6sr42methyl1himidazol4yl2oxo6235trichlorophenylcyclohex3ene1carboxylate AT christopherglidewell crystalstructureofethyl1rs6sr42methyl1himidazol4yl2oxo6235trichlorophenylcyclohex3ene1carboxylate
_version_	1725730595894460416

Crystal structure of ethyl (1RS,6SR)-4-(2-methyl-1H-imidazol-4-yl)-2-oxo-6-(2,3,5-trichlorophenyl)cyclohex-3-ene-1-carboxylate

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