Removal of Metals by Sulphide Precipitation Using Na₂S and HS⁻-Solution

• Main Authors: Hanna Prokkola, Emma-Tuulia Nurmesniemi, Ulla Lassi
• Format: Article
• Language: English
• Published: MDPI AG 2020-09-01
• Series: ChemEngineering
• Subjects: acid mine drainage; precipitation; metal sulphides; metal hydroxides
• Online Access: https://www.mdpi.com/2305-7084/4/3/51

Precipitation of metals as metal sulphides is a practical way to recover metals from mine water. Sulphide precipitation is useful since many metals are very sparingly soluble as sulphides. Precipitation is also pH dependent. This article investigates the precipitation of metals individually as sulphides and assesses which metals are precipitated as metal hydroxides by adjustment of the pH. The precipitation of different metals as sulphides was studied to determine the conditions under which the HS⁻ solution from the sulphate reduction reaction could be used for precipitation. H₂S gas and ionic HS⁻ produced during anaerobic treatment could be recycled from the process to precipitate metals in acidic mine drainage (AMD) prior to anaerobic treatment (Biological sulphate reduction), thereby recovering several metals. Precipitation of metals with HS⁻ was fast and produced fine precipitates. The pH of acid mine water is about 2–4, and it can be adjusted to pH 5.5 before sulphide precipitation, while the precipitation, on the other hand, requires a sulphide solution with pH at 8 and the sulphide in HS⁻ form. This prevents H₂S formation and mitigates the risk posed from the evaporation of toxic hydrogen sulphur gas. This is a lower increase than is required for hydroxide precipitation, in which pH is typically raised to approximately nine. After precipitation, metal concentrations ranged from 1 to 30 μg/L.